Cargando…

Alkaline-Earth-Catalyzed Dehydrocoupling of Amines and Boranes

Dehydrocoupling reactions between the boranes HBpin and 9-borabicyclo[3.3.1]nonane and a range of amines and anilines ensue under very mild reaction conditions in the presence of a simple β-diketiminato magnesium n-butyl precatalyst. The facility of the reactions is suggested to be a function of the...

Descripción completa

Detalles Bibliográficos
Autores principales:	Liptrot, David J, Hill, Michael S, Mahon, Mary F, Wilson, Andrew S S
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	WILEY-VCH Verlag 2015
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4674969/ https://www.ncbi.nlm.nih.gov/pubmed/26360523 http://dx.doi.org/10.1002/anie.201505949

Ejemplares similares

Magnesocenophane‐Catalyzed Amine Borane Dehydrocoupling
por: Wirtz, Lisa, et al.
Publicado: (2020)

Iron Catalyzed Dehydrocoupling of Amine‐ and Phosphine‐Boranes
por: Coles, Nathan T., et al.
Publicado: (2017)

P–C-Activated Bimetallic Rhodium Xantphos Complexes: Formation and Catalytic Dehydrocoupling of Amine–Boranes**
por: Johnson, Heather C, et al.
Publicado: (2015)

Calix[4]pyrrolato Aluminate Catalyzes the Dehydrocoupling of Phenylphosphine Borane to High Molar Weight Polymers
por: Schön, Florian, et al.
Publicado: (2022)

Probing the second dehydrogenation step in ammonia-borane dehydrocoupling: characterization and reactivity of the key intermediate, B-(cyclotriborazanyl)amine-borane
por: Kalviri, Hassan A., et al.
Publicado: (2015)

A Highly Active Bidentate Magnesium Catalyst for Amine‐Borane Dehydrocoupling: Kinetic and Mechanistic Studies
por: Ried, Alexander C. A., et al.
Publicado: (2019)

Computational Prediction of Ammonia-Borane Dehydrocoupling and Transfer Hydrogenation of Ketones and Imines Catalyzed by SCS Nickel Pincer Complexes
por: Qiu, Bing, et al.
Publicado: (2019)

Effect of the Phosphine Steric and Electronic Profile on the Rh-Promoted Dehydrocoupling of Phosphine–Boranes
por: Hooper, Thomas N., et al.
Publicado: (2014)

Alkaline-Earth-Promoted CO Homologation and Reductive Catalysis
por: Anker, Mathew D, et al.
Publicado: (2015)

Thermally Induced Silane Dehydrocoupling on Silicon Nanostructures
por: Kim, Dokyoung, et al.
Publicado: (2016)

Titanium-Mediated Reduction of Carboxamides to Amines with Borane–Ammonia
por: Ramachandran, P. Veeraraghavan, et al.
Publicado: (2023)

Propylamine–borane
por: Gainsford, Graeme J., et al.
Publicado: (2009)

Stereochemistry Controls Dihydrogen Bonding Strengths in Chiral Amine Boranes Adducts
por: Kemper, Michael, et al.
Publicado: (2022)

The Simplest Amino‐borane H(2)B=NH(2) Trapped on a Rhodium Dimer: Pre‐Catalysts for Amine–Borane Dehydropolymerization
por: Kumar, Amit, et al.
Publicado: (2016)

Amine–Borane Dehydropolymerization: Challenges and Opportunities
por: Colebatch, Annie L., et al.
Publicado: (2018)

Room Temperature Reduction of Titanium Tetrachloride-Activated Nitriles to Primary Amines with Ammonia-Borane
por: Ramachandran, P. Veeraraghavan, et al.
Publicado: (2022)

Metal-Free Hydrogenation Catalyzed by an Air-Stable Borane: Use of Solvent as a Frustrated Lewis Base**
por: Scott, Daniel J, et al.
Publicado: (2014)

Dehydrogenation of Amine–Boranes Using p‐Block Compounds
por: Boom, Devin H. A., et al.
Publicado: (2019)

Dehydrocoupling of phosphine–boranes using the [RhCp*Me(PMe(3))(CH(2)Cl(2))][BAr(F)(4)] precatalyst: stoichiometric and catalytic studies
por: Hooper, Thomas N., et al.
Publicado: (2016)

Toward Transition‐Metal‐Templated Construction of Arylated B(4) Chains by Dihydroborane Dehydrocoupling
por: Lenczyk, Carsten, et al.
Publicado: (2019)

Well‐Defined, Molecular Bismuth Compounds: Catalysts in Photochemically Induced Radical Dehydrocoupling Reactions
por: Ramler, Jacqueline, et al.
Publicado: (2020)

Inducing Propeller Chirality in Triaryl Boranes with Chiral Amines
por: Kemper, Michael, et al.
Publicado: (2022)

Correction: Dehydrocoupling of phosphine–boranes using the [RhCp*Me(PMe(3))(CH(2)Cl(2))][BAr(F)(4)] precatalyst: stoichiometric and catalytic studies
por: Hooper, Thomas N., et al.
Publicado: (2016)

Alkaline‐Earth Metal Mediated Benzene‐to‐Biphenyl Coupling
por: Mai, Jonathan, et al.
Publicado: (2022)

Retraction: Monodispersed palladium–cobalt alloy nanoparticles assembled on poly(N-vinyl-pyrrolidone) (PVP) as a highly effective catalyst for dimethylamine borane (DMAB) dehydrocoupling
por: Fisher, Laura
Publicado: (2021)

Step-growth titanium-catalysed dehydropolymerisation of amine–boranes
por: Jurca, Titel, et al.
Publicado: (2018)

Tris(pentafluorophenyl)borane‐Catalyzed Carbenium Ion Generation and Autocatalytic Pyrazole Synthesis—A Computational and Experimental Study
por: Dasgupta, Ayan, et al.
Publicado: (2021)

Dehydropolymerisation of Methylamine Borane and an N‐Substituted Primary Amine Borane Using a PNP Fe Catalyst
por: Anke, Felix, et al.
Publicado: (2020)

Hypolipidemic Activity of Amine-Borane Aducts of Cyclohexylamine and Toluidine in Rodents
por: Burnham, Bruce S., et al.
Publicado: (1995)

Chromium‐Catalyzed Alkylation of Amines by Alcohols
por: Kallmeier, Fabian, et al.
Publicado: (2020)

Hydrosilane σ‐Adduct Intermediates in an Adaptive Zinc‐Catalyzed Cross‐dehydrocoupling of Si−H and O−H Bonds
por: Patnaik, Smita, et al.
Publicado: (2021)

Tris(pentafluorophenyl)borane-Catalyzed Reactions Using Silanes
por: Hackel, Taylor, et al.
Publicado: (2019)

Bi(I)-Catalyzed Transfer-Hydrogenation with Ammonia-Borane
por: Wang, Feng, et al.
Publicado: (2019)

Titanium‐Catalyzed Intermolecular Hydroaminoalkylation of Alkenes with Tertiary Amines
por: Geik, Dennis, et al.
Publicado: (2021)

Chemoselectivity in the Dehydrocoupling Synthesis of Higher Molecular Weight Polysilanes
por: Lunzer, Florian, et al.
Publicado: (2010)

An Isolable Bis(Silanone–Borane) Adduct
por: Luecke, Marcel‐Philip, et al.
Publicado: (2020)

Efficient Organocatalytic Dehydrogenation of Ammonia Borane
por: Hasenbeck, Max, et al.
Publicado: (2019)

Amine–Boranes as Transfer Hydrogenation and Hydrogenation Reagents: A Mechanistic Perspective
por: Lau, Samantha, et al.
Publicado: (2021)

Boric Ester-Type Molten Salt via Dehydrocoupling Reaction
por: Matsumi, Noriyoshi, et al.
Publicado: (2014)

Antimony-ligated dysprosium single-molecule magnets as catalysts for stibine dehydrocoupling
por: Pugh, Thomas, et al.
Publicado: (2017)

Cannot write session to /tmp/vufind_sessions/sess_n0h4rpon5ugdo31e3ndq3k6hi8