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Constant Electric and Magnetic Fields Effect on the Structuring and Thermomechanical and Thermophysical Properties of Nanocomposites Formed from Pectin–Cu(2+)–Polyethyleneimine Interpolyelectrolyte–Metal Complexes
Applying wide-angle X-ray scattering method, thermomechanical analysis, and differential scanning calorimetry, the structural organization and properties of nanocomposites formed by chemical reduction of Сu(2+) cations in the interpolyelectrolyte–metal complex (pectin–Cu(2+)–polyethyleneimine) under...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer US
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4675758/ https://www.ncbi.nlm.nih.gov/pubmed/26659610 http://dx.doi.org/10.1186/s11671-015-1181-z |
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author | Demchenko, V. Shtompel’, V. Riabov, S. Lysenkov, E. |
author_facet | Demchenko, V. Shtompel’, V. Riabov, S. Lysenkov, E. |
author_sort | Demchenko, V. |
collection | PubMed |
description | Applying wide-angle X-ray scattering method, thermomechanical analysis, and differential scanning calorimetry, the structural organization and properties of nanocomposites formed by chemical reduction of Сu(2+) cations in the interpolyelectrolyte–metal complex (pectin–Cu(2+)–polyethyleneimine) under the influence of a constant magnetic and electric fields have been studied. It has been found that the chemical reduction of Cu(2+) cations in the interpolyelectrolyte–metal complex bulk under constant electric and magnetic fields leads to formation of nanocomposite consisting of interpolyelectrolyte complex, including pectin–polyethyleneimine and nanoparticles of the metal Cu phase, whereas nanocomposite with Cu/Cu(2)O nanoparticles is formed in original state (without any field). It was observed that, under constant field, nanocomposites obtained have higher structural glass-transition temperatures and thermal stability. |
format | Online Article Text |
id | pubmed-4675758 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | Springer US |
record_format | MEDLINE/PubMed |
spelling | pubmed-46757582015-12-20 Constant Electric and Magnetic Fields Effect on the Structuring and Thermomechanical and Thermophysical Properties of Nanocomposites Formed from Pectin–Cu(2+)–Polyethyleneimine Interpolyelectrolyte–Metal Complexes Demchenko, V. Shtompel’, V. Riabov, S. Lysenkov, E. Nanoscale Res Lett Nano Express Applying wide-angle X-ray scattering method, thermomechanical analysis, and differential scanning calorimetry, the structural organization and properties of nanocomposites formed by chemical reduction of Сu(2+) cations in the interpolyelectrolyte–metal complex (pectin–Cu(2+)–polyethyleneimine) under the influence of a constant magnetic and electric fields have been studied. It has been found that the chemical reduction of Cu(2+) cations in the interpolyelectrolyte–metal complex bulk under constant electric and magnetic fields leads to formation of nanocomposite consisting of interpolyelectrolyte complex, including pectin–polyethyleneimine and nanoparticles of the metal Cu phase, whereas nanocomposite with Cu/Cu(2)O nanoparticles is formed in original state (without any field). It was observed that, under constant field, nanocomposites obtained have higher structural glass-transition temperatures and thermal stability. Springer US 2015-12-10 /pmc/articles/PMC4675758/ /pubmed/26659610 http://dx.doi.org/10.1186/s11671-015-1181-z Text en © Demchenko et al. 2015 Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. |
spellingShingle | Nano Express Demchenko, V. Shtompel’, V. Riabov, S. Lysenkov, E. Constant Electric and Magnetic Fields Effect on the Structuring and Thermomechanical and Thermophysical Properties of Nanocomposites Formed from Pectin–Cu(2+)–Polyethyleneimine Interpolyelectrolyte–Metal Complexes |
title | Constant Electric and Magnetic Fields Effect on the Structuring and Thermomechanical and Thermophysical Properties of Nanocomposites Formed from Pectin–Cu(2+)–Polyethyleneimine Interpolyelectrolyte–Metal Complexes |
title_full | Constant Electric and Magnetic Fields Effect on the Structuring and Thermomechanical and Thermophysical Properties of Nanocomposites Formed from Pectin–Cu(2+)–Polyethyleneimine Interpolyelectrolyte–Metal Complexes |
title_fullStr | Constant Electric and Magnetic Fields Effect on the Structuring and Thermomechanical and Thermophysical Properties of Nanocomposites Formed from Pectin–Cu(2+)–Polyethyleneimine Interpolyelectrolyte–Metal Complexes |
title_full_unstemmed | Constant Electric and Magnetic Fields Effect on the Structuring and Thermomechanical and Thermophysical Properties of Nanocomposites Formed from Pectin–Cu(2+)–Polyethyleneimine Interpolyelectrolyte–Metal Complexes |
title_short | Constant Electric and Magnetic Fields Effect on the Structuring and Thermomechanical and Thermophysical Properties of Nanocomposites Formed from Pectin–Cu(2+)–Polyethyleneimine Interpolyelectrolyte–Metal Complexes |
title_sort | constant electric and magnetic fields effect on the structuring and thermomechanical and thermophysical properties of nanocomposites formed from pectin–cu(2+)–polyethyleneimine interpolyelectrolyte–metal complexes |
topic | Nano Express |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4675758/ https://www.ncbi.nlm.nih.gov/pubmed/26659610 http://dx.doi.org/10.1186/s11671-015-1181-z |
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