Cargando…

Constant Electric and Magnetic Fields Effect on the Structuring and Thermomechanical and Thermophysical Properties of Nanocomposites Formed from Pectin–Cu(2+)–Polyethyleneimine Interpolyelectrolyte–Metal Complexes

Applying wide-angle X-ray scattering method, thermomechanical analysis, and differential scanning calorimetry, the structural organization and properties of nanocomposites formed by chemical reduction of Сu(2+) cations in the interpolyelectrolyte–metal complex (pectin–Cu(2+)–polyethyleneimine) under...

Descripción completa

Detalles Bibliográficos
Autores principales: Demchenko, V., Shtompel’, V., Riabov, S., Lysenkov, E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4675758/
https://www.ncbi.nlm.nih.gov/pubmed/26659610
http://dx.doi.org/10.1186/s11671-015-1181-z
_version_ 1782405054583537664
author Demchenko, V.
Shtompel’, V.
Riabov, S.
Lysenkov, E.
author_facet Demchenko, V.
Shtompel’, V.
Riabov, S.
Lysenkov, E.
author_sort Demchenko, V.
collection PubMed
description Applying wide-angle X-ray scattering method, thermomechanical analysis, and differential scanning calorimetry, the structural organization and properties of nanocomposites formed by chemical reduction of Сu(2+) cations in the interpolyelectrolyte–metal complex (pectin–Cu(2+)–polyethyleneimine) under the influence of a constant magnetic and electric fields have been studied. It has been found that the chemical reduction of Cu(2+) cations in the interpolyelectrolyte–metal complex bulk under constant electric and magnetic fields leads to formation of nanocomposite consisting of interpolyelectrolyte complex, including pectin–polyethyleneimine and nanoparticles of the metal Cu phase, whereas nanocomposite with Cu/Cu(2)O nanoparticles is formed in original state (without any field). It was observed that, under constant field, nanocomposites obtained have higher structural glass-transition temperatures and thermal stability.
format Online
Article
Text
id pubmed-4675758
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher Springer US
record_format MEDLINE/PubMed
spelling pubmed-46757582015-12-20 Constant Electric and Magnetic Fields Effect on the Structuring and Thermomechanical and Thermophysical Properties of Nanocomposites Formed from Pectin–Cu(2+)–Polyethyleneimine Interpolyelectrolyte–Metal Complexes Demchenko, V. Shtompel’, V. Riabov, S. Lysenkov, E. Nanoscale Res Lett Nano Express Applying wide-angle X-ray scattering method, thermomechanical analysis, and differential scanning calorimetry, the structural organization and properties of nanocomposites formed by chemical reduction of Сu(2+) cations in the interpolyelectrolyte–metal complex (pectin–Cu(2+)–polyethyleneimine) under the influence of a constant magnetic and electric fields have been studied. It has been found that the chemical reduction of Cu(2+) cations in the interpolyelectrolyte–metal complex bulk under constant electric and magnetic fields leads to formation of nanocomposite consisting of interpolyelectrolyte complex, including pectin–polyethyleneimine and nanoparticles of the metal Cu phase, whereas nanocomposite with Cu/Cu(2)O nanoparticles is formed in original state (without any field). It was observed that, under constant field, nanocomposites obtained have higher structural glass-transition temperatures and thermal stability. Springer US 2015-12-10 /pmc/articles/PMC4675758/ /pubmed/26659610 http://dx.doi.org/10.1186/s11671-015-1181-z Text en © Demchenko et al. 2015 Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
spellingShingle Nano Express
Demchenko, V.
Shtompel’, V.
Riabov, S.
Lysenkov, E.
Constant Electric and Magnetic Fields Effect on the Structuring and Thermomechanical and Thermophysical Properties of Nanocomposites Formed from Pectin–Cu(2+)–Polyethyleneimine Interpolyelectrolyte–Metal Complexes
title Constant Electric and Magnetic Fields Effect on the Structuring and Thermomechanical and Thermophysical Properties of Nanocomposites Formed from Pectin–Cu(2+)–Polyethyleneimine Interpolyelectrolyte–Metal Complexes
title_full Constant Electric and Magnetic Fields Effect on the Structuring and Thermomechanical and Thermophysical Properties of Nanocomposites Formed from Pectin–Cu(2+)–Polyethyleneimine Interpolyelectrolyte–Metal Complexes
title_fullStr Constant Electric and Magnetic Fields Effect on the Structuring and Thermomechanical and Thermophysical Properties of Nanocomposites Formed from Pectin–Cu(2+)–Polyethyleneimine Interpolyelectrolyte–Metal Complexes
title_full_unstemmed Constant Electric and Magnetic Fields Effect on the Structuring and Thermomechanical and Thermophysical Properties of Nanocomposites Formed from Pectin–Cu(2+)–Polyethyleneimine Interpolyelectrolyte–Metal Complexes
title_short Constant Electric and Magnetic Fields Effect on the Structuring and Thermomechanical and Thermophysical Properties of Nanocomposites Formed from Pectin–Cu(2+)–Polyethyleneimine Interpolyelectrolyte–Metal Complexes
title_sort constant electric and magnetic fields effect on the structuring and thermomechanical and thermophysical properties of nanocomposites formed from pectin–cu(2+)–polyethyleneimine interpolyelectrolyte–metal complexes
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4675758/
https://www.ncbi.nlm.nih.gov/pubmed/26659610
http://dx.doi.org/10.1186/s11671-015-1181-z
work_keys_str_mv AT demchenkov constantelectricandmagneticfieldseffectonthestructuringandthermomechanicalandthermophysicalpropertiesofnanocompositesformedfrompectincu2polyethyleneimineinterpolyelectrolytemetalcomplexes
AT shtompelv constantelectricandmagneticfieldseffectonthestructuringandthermomechanicalandthermophysicalpropertiesofnanocompositesformedfrompectincu2polyethyleneimineinterpolyelectrolytemetalcomplexes
AT riabovs constantelectricandmagneticfieldseffectonthestructuringandthermomechanicalandthermophysicalpropertiesofnanocompositesformedfrompectincu2polyethyleneimineinterpolyelectrolytemetalcomplexes
AT lysenkove constantelectricandmagneticfieldseffectonthestructuringandthermomechanicalandthermophysicalpropertiesofnanocompositesformedfrompectincu2polyethyleneimineinterpolyelectrolytemetalcomplexes