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Ether Cleavage Re-Investigated: Elucidating the Mechanism of BBr(3)-Facilitated Demethylation of Aryl Methyl Ethers

One of the most well-known, highly utilized reagents for ether cleavage is boron tribromide (BBr(3)), and this reagent is frequently employed in a 1:1 stoichiometric ratio with ethers. Density functional theory calculations predict a new mechanistic pathway involving charged intermediates for ether...

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Detalles Bibliográficos
Autores principales:	Kosak, Talon M, Conrad, Heidi A, Korich, Andrew L, Lord, Richard L
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	WILEY-VCH Verlag 2015
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4676310/ https://www.ncbi.nlm.nih.gov/pubmed/26693209 http://dx.doi.org/10.1002/ejoc.201501042

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