Alkaline-Earth-Promoted CO Homologation and Reductive Catalysis

Reaction between a β-diketiminato magnesium hydride and carbon monoxide results in the isolation of a dimeric cis-enediolate species through the reductive coupling of two CO molecules. Under catalytic conditions with PhSiH(3), an observable magnesium formyl species may be intercepted for the mild re...

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Detalles Bibliográficos
Autores principales: Anker, Mathew D, Hill, Michael S, Lowe, John P, Mahon, Mary F
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4678424/
https://www.ncbi.nlm.nih.gov/pubmed/26220407
http://dx.doi.org/10.1002/anie.201505851
Descripción
Sumario:Reaction between a β-diketiminato magnesium hydride and carbon monoxide results in the isolation of a dimeric cis-enediolate species through the reductive coupling of two CO molecules. Under catalytic conditions with PhSiH(3), an observable magnesium formyl species may be intercepted for the mild reductive cleavage of the CO triple bond.

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