Alkaline-Earth-Promoted CO Homologation and Reductive Catalysis

Reaction between a β-diketiminato magnesium hydride and carbon monoxide results in the isolation of a dimeric cis-enediolate species through the reductive coupling of two CO molecules. Under catalytic conditions with PhSiH(3), an observable magnesium formyl species may be intercepted for the mild re...

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Autores principales: Anker, Mathew D, Hill, Michael S, Lowe, John P, Mahon, Mary F
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4678424/
https://www.ncbi.nlm.nih.gov/pubmed/26220407
http://dx.doi.org/10.1002/anie.201505851
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author Anker, Mathew D
Hill, Michael S
Lowe, John P
Mahon, Mary F
author_facet Anker, Mathew D
Hill, Michael S
Lowe, John P
Mahon, Mary F
author_sort Anker, Mathew D
collection PubMed
description Reaction between a β-diketiminato magnesium hydride and carbon monoxide results in the isolation of a dimeric cis-enediolate species through the reductive coupling of two CO molecules. Under catalytic conditions with PhSiH(3), an observable magnesium formyl species may be intercepted for the mild reductive cleavage of the CO triple bond.
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spelling pubmed-46784242015-12-22 Alkaline-Earth-Promoted CO Homologation and Reductive Catalysis Anker, Mathew D Hill, Michael S Lowe, John P Mahon, Mary F Angew Chem Int Ed Engl Communications Reaction between a β-diketiminato magnesium hydride and carbon monoxide results in the isolation of a dimeric cis-enediolate species through the reductive coupling of two CO molecules. Under catalytic conditions with PhSiH(3), an observable magnesium formyl species may be intercepted for the mild reductive cleavage of the CO triple bond. WILEY-VCH Verlag 2015-08-17 2015-07-24 /pmc/articles/PMC4678424/ /pubmed/26220407 http://dx.doi.org/10.1002/anie.201505851 Text en © 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. https://creativecommons.org/licenses/by/4.0/ © 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Anker, Mathew D
Hill, Michael S
Lowe, John P
Mahon, Mary F
Alkaline-Earth-Promoted CO Homologation and Reductive Catalysis
title Alkaline-Earth-Promoted CO Homologation and Reductive Catalysis
title_full Alkaline-Earth-Promoted CO Homologation and Reductive Catalysis
title_fullStr Alkaline-Earth-Promoted CO Homologation and Reductive Catalysis
title_full_unstemmed Alkaline-Earth-Promoted CO Homologation and Reductive Catalysis
title_short Alkaline-Earth-Promoted CO Homologation and Reductive Catalysis
title_sort alkaline-earth-promoted co homologation and reductive catalysis
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4678424/
https://www.ncbi.nlm.nih.gov/pubmed/26220407
http://dx.doi.org/10.1002/anie.201505851
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AT hillmichaels alkalineearthpromotedcohomologationandreductivecatalysis
AT lowejohnp alkalineearthpromotedcohomologationandreductivecatalysis
AT mahonmaryf alkalineearthpromotedcohomologationandreductivecatalysis

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