Alkaline-Earth-Promoted CO Homologation and Reductive Catalysis

Reaction between a β-diketiminato magnesium hydride and carbon monoxide results in the isolation of a dimeric cis-enediolate species through the reductive coupling of two CO molecules. Under catalytic conditions with PhSiH(3), an observable magnesium formyl species may be intercepted for the mild re...

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Detalles Bibliográficos
Autores principales: Anker, Mathew D, Hill, Michael S, Lowe, John P, Mahon, Mary F
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4678424/
https://www.ncbi.nlm.nih.gov/pubmed/26220407
http://dx.doi.org/10.1002/anie.201505851

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4678424/
https://www.ncbi.nlm.nih.gov/pubmed/26220407
http://dx.doi.org/10.1002/anie.201505851

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