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Alkaline-Earth-Promoted CO Homologation and Reductive Catalysis

Reaction between a β-diketiminato magnesium hydride and carbon monoxide results in the isolation of a dimeric cis-enediolate species through the reductive coupling of two CO molecules. Under catalytic conditions with PhSiH(3), an observable magnesium formyl species may be intercepted for the mild re...

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Detalles Bibliográficos
Autores principales:	Anker, Mathew D, Hill, Michael S, Lowe, John P, Mahon, Mary F
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	WILEY-VCH Verlag 2015
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4678424/ https://www.ncbi.nlm.nih.gov/pubmed/26220407 http://dx.doi.org/10.1002/anie.201505851

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