Nanoporous Materials Can Tune the Critical Point of a Pure Substance

Molecular simulations and NMR relaxometry experiments demonstrate that pure benzene or xylene confined in isoreticular metal–organic frameworks (IRMOFs) exhibit true vapor–liquid phase equilibria where the effective critical point may be reduced by tuning the structure of the MOF. Our results are co...

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Detalles Bibliográficos
Autores principales: Braun, Efrem, Chen, Joseph J, Schnell, Sondre K, Lin, Li-Chiang, Reimer, Jeffrey A, Smit, Berend
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4678509/
https://www.ncbi.nlm.nih.gov/pubmed/26419318
http://dx.doi.org/10.1002/anie.201506865

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