Cargando…

Carbon–carbon bond cleavage for Cu-mediated aromatic trifluoromethylations and pentafluoroethylations

This short review highlights the copper-mediated fluoroalkylation using perfluoroalkylated carboxylic acid derivatives. Carbon–carbon bond cleavage of perfluoroalkylated carboxylic acid derivatives takes place in fluoroalkylation reactions at high temperature (150–200 °C) or under basic conditions t...

Descripción completa

Detalles Bibliográficos
Autores principales:	Sugiishi, Tsuyuka, Amii, Hideki, Aikawa, Kohsuke, Mikami, Koichi
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2015
Materias:	Review
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4685791/ https://www.ncbi.nlm.nih.gov/pubmed/26734112 http://dx.doi.org/10.3762/bjoc.11.286

Ejemplares similares

Cu-catalyzed trifluoromethylation of aryl iodides with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide
por: Nakamura, Yuzo, et al.
Publicado: (2013)

Nucleophilic fluoroalkylation/cyclization route to fluorinated phthalides
por: Inaba, Masanori, et al.
Publicado: (2018)

Synthesis and Characterization of Tetrakis(pentafluoroethyl)aluminate
por: Tiessen, Natalia, et al.
Publicado: (2020)

Tris(pentafluoroethyl)silanol Derivatives and the Lewis Amphoteric Tris(pentafluoroethyl)silanolate Anion, [Si(C(2)F(5))(3)O](−)
por: Tiessen, Natalia, et al.
Publicado: (2021)

An Unusual Carbon-Carbon Bond Cleavage Reaction During Phosphinothricin Biosynthesis
por: Cicchillo, Robert M., et al.
Publicado: (2009)

Cleavage of a carbon–fluorine bond by an engineered cysteine dioxygenase
por: Li, Jiasong, et al.
Publicado: (2018)

Tris(pentafluoroethyl)difluorophosphorane: A Versatile Fluoride Acceptor for Transition Metal Chemistry
por: Föhrenbacher, Steffen A., et al.
Publicado: (2021)

Chemocatalytic value addition of glucose without carbon–carbon bond cleavage/formation reactions: an overview
por: Dutta, Saikat, et al.
Publicado: (2022)

Aromatic thiol-mediated cleavage of N–O bonds enables chemical ubiquitylation of folded proteins
por: Weller, Caroline E., et al.
Publicado: (2016)

Divergent reactivities in fluoronation of allylic alcohols: synthesis of Z-fluoroalkenes via carbon–carbon bond cleavage
por: Liu, Tang-Lin, et al.
Publicado: (2017)

Asymmetric [3 + 2] cycloaddition of donor–acceptor aziridines with aldehydes via carbon–carbon bond cleavage
por: Liao, Yuting, et al.
Publicado: (2016)

Palladium(ii)-catalyzed synthesis of dibenzothiophene derivatives via the cleavage of carbon–sulfur and carbon–hydrogen bonds
por: Tobisu, Mamoru, et al.
Publicado: (2016)

Tetrakis(pentafluoroethyl)gallate, [Ga(C(2)F(5))(4)](−), Ionic Liquids
por: Biller, Harry, et al.
Publicado: (2021)

CO/O(2) assisted oxidative carbon–carbon and carbon–heteroatom bond cleavage for the synthesis of oxosulfonates from DMSO and olefins
por: Shao, Ailong, et al.
Publicado: (2017)

Organic amine mediated cleavage of C(aromatic)–C(α) bonds in lignin and its platform molecules
por: Xin, Yu, et al.
Publicado: (2021)

Cu and Hydroquinone for the Trifluoromethylation of Unprotected Phenols
por: Pletz, Jakob, et al.
Publicado: (2018)

Diastereoselective Additive Trifluoromethylation/Halogenation of Isoxazole Triflones: Synthesis of All-Carbon-Functionalized Trifluoromethyl Isoxazoline Triflones
por: Kawai, Hiroyuki, et al.
Publicado: (2014)

Halogen bonding with carbon: directional assembly of non-derivatised aromatic carbon systems into robust supramolecular ladder architectures
por: Vainauskas, Jogirdas, et al.
Publicado: (2023)

Metal-Free Trifluoromethylation of Aromatic and Heteroaromatic Aldehydes and Ketones
por: Qiao, Yupu, et al.
Publicado: (2014)

Mechanochemical Conversion of Aromatic Amines to Aryl Trifluoromethyl Ethers
por: Jakubczyk, Michał, et al.
Publicado: (2022)

Occurrence of Double Bond in π-Aromatic Rings: An Easy Way to Design Doubly Aromatic Carbon-Metal Structures
por: Tkachenko, Nikolay V., et al.
Publicado: (2021)

Palladium‐Catalyzed Cascade Carbonylation to α,β‐Unsaturated Piperidones via Selective Cleavage of Carbon–Carbon Triple Bonds
por: Ge, Yao, et al.
Publicado: (2021)

Cu-Mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF(3)
por: Jiang, Xueliang, et al.
Publicado: (2013)

Nanostructured Carbon Nitride for Continuous-Flow Trifluoromethylation of (Hetero)arenes
por: Sivo, Alessandra, et al.
Publicado: (2023)

Evidence of the Lewis‐Amphoteric Character of Tris(pentafluoroethyl)silanide, [Si(C(2)F(5))(3)](−)
por: Tiessen, Natalia, et al.
Publicado: (2021)

Copper-catalyzed asymmetric methylation of fluoroalkylated pyruvates with dimethylzinc
por: Aikawa, Kohsuke, et al.
Publicado: (2018)

Aromatization modulates the activity of small organic molecules as promoters for carbon–halogen bond activation
por: Yang, Huan, et al.
Publicado: (2018)

Cu-catalyzed C–C bond formation of vinylidene cyclopropanes with carbon nucleophiles
por: Chen, Jichao, et al.
Publicado: (2019)

Vibrational control of selective bond cleavage in dissociative chemisorption of methanol on Cu(111)
por: Chen, Jialu, et al.
Publicado: (2018)

Comparison of carbon-sulfur and carbon-amine bond in therapeutic drug: 4β-S-aromatic heterocyclic podophyllum derivatives display antitumor activity
por: Li, Jian-Long, et al.
Publicado: (2015)

Highly Transparent Aromatic Polyamides from Unsymmetrical Diamine with Trifluoromethyl Groups
por: Kim, Seong Jong, et al.
Publicado: (2022)

Cu-Catalyzed Direct Amidation of Aromatic C–H Bonds: An Access to Arylamines
por: Xu, Hui, et al.
Publicado: (2014)

Electron/energy co-transfer behavior and reducibility of Cu-chlorophyllin-bonded carbon-dots
por: Ji, Tian-Hao, et al.
Publicado: (2020)

Correction: Cu-catalyzed C–C bond formation of vinylidene cyclopropanes with carbon nucleophiles
por: Chen, Jichao, et al.
Publicado: (2020)

Bond cleavage of lignin model compounds into aromatic monomers using supported metal catalysts in supercritical water
por: Yamaguchi, Aritomo, et al.
Publicado: (2017)

Novel carbon–carbon bond formations for biocatalysis
por: Resch, Verena, et al.
Publicado: (2011)

Chlorido(η(4)-1,5-cyclooctadiene)[(pentafluoroethyl)diphenylphosphane]iridium(I)
por: Choate, Michelle M., et al.
Publicado: (2010)

Ionic Liquids as Working Fluids for Heat Storage Applications: Decomposition Behavior of N-Butyl-N-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate
por: Nardelli, Francesca, et al.
Publicado: (2023)

Recent advances in direct trifluoromethylation of olefinic C–H bonds
por: Yang, Cao, et al.
Publicado: (2019)

Interfacial Bonding Improvement through Nickel Decoration on Carbon Nanotubes in Carbon Nanotubes/Cu Composite Foams Reinforced Copper Matrix Composites
por: Wang, Dan, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_55n15k56ug95a73anv38velt9v