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Copper-catalyzed stereoselective conjugate addition of alkylboranes to alkynoates

A copper-catalyzed conjugate addition of alkylboron compounds (alkyl-9-BBN, prepared by hydroboration of alkenes with 9-BBN-H) to alkynoates to form β-disubstituted acrylates is reported. The addition occurred in a formal syn-hydroalkylation mode. The syn stereoselectivity was excellent regardless o...

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Detalles Bibliográficos
Autores principales:	Wakamatsu, Takamichi, Nagao, Kazunori, Ohmiya, Hirohisa, Sawamura, Masaya
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2015
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4685882/ https://www.ncbi.nlm.nih.gov/pubmed/26734092 http://dx.doi.org/10.3762/bjoc.11.265

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