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Six-Coordinate Zinc Porphyrins for Template-Directed Synthesis of Spiro-Fused Nanorings
[Image: see text] Five-coordinate geometry is the standard binding mode of zinc porphyrins with pyridine ligands. Here we show that pseudo-octahedral six-coordinate zinc porphyrin complexes can also be formed in solution, by taking advantage of the chelate effect. UV–vis–NIR titrations indicate that...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2015
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4686216/ https://www.ncbi.nlm.nih.gov/pubmed/26536147 http://dx.doi.org/10.1021/jacs.5b10126 |