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What is an ‘ideally imperfect’ crystal? Is kinematical theory appropriate?
Most materials are crystalline because atoms and molecules tend to form ordered arrangements, and since the interatomic distances are comparable with the wavelength of X-rays, their interaction creates diffraction patterns. The intensity in these patterns changes with crystal quality. Perfect crysta...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2016
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4689186/ https://www.ncbi.nlm.nih.gov/pubmed/26697866 http://dx.doi.org/10.1107/S2053273315018975 |
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author | Fewster, Paul F. |
author_facet | Fewster, Paul F. |
author_sort | Fewster, Paul F. |
collection | PubMed |
description | Most materials are crystalline because atoms and molecules tend to form ordered arrangements, and since the interatomic distances are comparable with the wavelength of X-rays, their interaction creates diffraction patterns. The intensity in these patterns changes with crystal quality. Perfect crystals, e.g. semiconductors, fit well to dynamical theory, whereas crystals that reveal the stereochemistry of complex biological molecules, the structure of organic and inorganic molecules and powders are required to be fragmented (termed ‘ideally imperfect’) to justify the use of the simpler kinematical theory. New experimental results of perfect and imperfect crystals are interpreted with a fundamental description of diffraction, which does not need fragmented crystals but just ubiquitous defects. The distribution of the intensity is modified and can influence the interpretation of the patterns. |
format | Online Article Text |
id | pubmed-4689186 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-46891862016-01-08 What is an ‘ideally imperfect’ crystal? Is kinematical theory appropriate? Fewster, Paul F. Acta Crystallogr A Found Adv Research Papers Most materials are crystalline because atoms and molecules tend to form ordered arrangements, and since the interatomic distances are comparable with the wavelength of X-rays, their interaction creates diffraction patterns. The intensity in these patterns changes with crystal quality. Perfect crystals, e.g. semiconductors, fit well to dynamical theory, whereas crystals that reveal the stereochemistry of complex biological molecules, the structure of organic and inorganic molecules and powders are required to be fragmented (termed ‘ideally imperfect’) to justify the use of the simpler kinematical theory. New experimental results of perfect and imperfect crystals are interpreted with a fundamental description of diffraction, which does not need fragmented crystals but just ubiquitous defects. The distribution of the intensity is modified and can influence the interpretation of the patterns. International Union of Crystallography 2016-01-01 /pmc/articles/PMC4689186/ /pubmed/26697866 http://dx.doi.org/10.1107/S2053273315018975 Text en © Paul F. Fewster 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Papers Fewster, Paul F. What is an ‘ideally imperfect’ crystal? Is kinematical theory appropriate? |
title | What is an ‘ideally imperfect’ crystal? Is kinematical theory appropriate? |
title_full | What is an ‘ideally imperfect’ crystal? Is kinematical theory appropriate? |
title_fullStr | What is an ‘ideally imperfect’ crystal? Is kinematical theory appropriate? |
title_full_unstemmed | What is an ‘ideally imperfect’ crystal? Is kinematical theory appropriate? |
title_short | What is an ‘ideally imperfect’ crystal? Is kinematical theory appropriate? |
title_sort | what is an ‘ideally imperfect’ crystal? is kinematical theory appropriate? |
topic | Research Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4689186/ https://www.ncbi.nlm.nih.gov/pubmed/26697866 http://dx.doi.org/10.1107/S2053273315018975 |
work_keys_str_mv | AT fewsterpaulf whatisanideallyimperfectcrystaliskinematicaltheoryappropriate |