Cargando…

What is an ‘ideally imperfect’ crystal? Is kinematical theory appropriate?

Most materials are crystalline because atoms and molecules tend to form ordered arrangements, and since the interatomic distances are comparable with the wavelength of X-rays, their interaction creates diffraction patterns. The intensity in these patterns changes with crystal quality. Perfect crysta...

Descripción completa

Detalles Bibliográficos
Autor principal: Fewster, Paul F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4689186/
https://www.ncbi.nlm.nih.gov/pubmed/26697866
http://dx.doi.org/10.1107/S2053273315018975
_version_ 1782406809779175424
author Fewster, Paul F.
author_facet Fewster, Paul F.
author_sort Fewster, Paul F.
collection PubMed
description Most materials are crystalline because atoms and molecules tend to form ordered arrangements, and since the interatomic distances are comparable with the wavelength of X-rays, their interaction creates diffraction patterns. The intensity in these patterns changes with crystal quality. Perfect crystals, e.g. semiconductors, fit well to dynamical theory, whereas crystals that reveal the stereochemistry of complex biological molecules, the structure of organic and inorganic molecules and powders are required to be fragmented (termed ‘ideally imperfect’) to justify the use of the simpler kinematical theory. New experimental results of perfect and imperfect crystals are interpreted with a fundamental description of diffraction, which does not need fragmented crystals but just ubiquitous defects. The distribution of the intensity is modified and can influence the interpretation of the patterns.
format Online
Article
Text
id pubmed-4689186
institution National Center for Biotechnology Information
language English
publishDate 2016
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-46891862016-01-08 What is an ‘ideally imperfect’ crystal? Is kinematical theory appropriate? Fewster, Paul F. Acta Crystallogr A Found Adv Research Papers Most materials are crystalline because atoms and molecules tend to form ordered arrangements, and since the interatomic distances are comparable with the wavelength of X-rays, their interaction creates diffraction patterns. The intensity in these patterns changes with crystal quality. Perfect crystals, e.g. semiconductors, fit well to dynamical theory, whereas crystals that reveal the stereochemistry of complex biological molecules, the structure of organic and inorganic molecules and powders are required to be fragmented (termed ‘ideally imperfect’) to justify the use of the simpler kinematical theory. New experimental results of perfect and imperfect crystals are interpreted with a fundamental description of diffraction, which does not need fragmented crystals but just ubiquitous defects. The distribution of the intensity is modified and can influence the interpretation of the patterns. International Union of Crystallography 2016-01-01 /pmc/articles/PMC4689186/ /pubmed/26697866 http://dx.doi.org/10.1107/S2053273315018975 Text en © Paul F. Fewster 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Papers
Fewster, Paul F.
What is an ‘ideally imperfect’ crystal? Is kinematical theory appropriate?
title What is an ‘ideally imperfect’ crystal? Is kinematical theory appropriate?
title_full What is an ‘ideally imperfect’ crystal? Is kinematical theory appropriate?
title_fullStr What is an ‘ideally imperfect’ crystal? Is kinematical theory appropriate?
title_full_unstemmed What is an ‘ideally imperfect’ crystal? Is kinematical theory appropriate?
title_short What is an ‘ideally imperfect’ crystal? Is kinematical theory appropriate?
title_sort what is an ‘ideally imperfect’ crystal? is kinematical theory appropriate?
topic Research Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4689186/
https://www.ncbi.nlm.nih.gov/pubmed/26697866
http://dx.doi.org/10.1107/S2053273315018975
work_keys_str_mv AT fewsterpaulf whatisanideallyimperfectcrystaliskinematicaltheoryappropriate