Branch-Selective Alkene Hydroarylation by Cooperative Destabilization: Iridium-Catalyzed ortho-Alkylation of Acetanilides

An iridium(I) catalyst system, modified with the wide-bite-angle and electron-deficient bisphosphine d(F)ppb (1,4-bis(di(pentafluorophenyl)phosphino)butane) promotes highly branch-selective hydroarylation reactions between diverse acetanilides and aryl- or alkyl-substituted alkenes. This provides di...

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Detalles Bibliográficos
Autores principales: Crisenza, Giacomo E M, Sokolova, Olga O, Bower, John F
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4691333/
https://www.ncbi.nlm.nih.gov/pubmed/26490739
http://dx.doi.org/10.1002/anie.201506581

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4691333/
https://www.ncbi.nlm.nih.gov/pubmed/26490739
http://dx.doi.org/10.1002/anie.201506581

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