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Sultones and Sultines via a Julia–Kocienski Reaction of Epoxides

The development of the homologous Julia–Kocienski reaction has led to the discovery of two new reaction modes of epoxides with sulfones. These pathways allow rapid and direct access to a range of γ-sultones and γ-sultines.

Detalles Bibliográficos
Autores principales: Smith, Geoffrey M T, Burton, Paul M, Bray, Christopher D
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4691334/
https://www.ncbi.nlm.nih.gov/pubmed/26503062
http://dx.doi.org/10.1002/anie.201508467
Descripción
Sumario:The development of the homologous Julia–Kocienski reaction has led to the discovery of two new reaction modes of epoxides with sulfones. These pathways allow rapid and direct access to a range of γ-sultones and γ-sultines.