Giant Spherical Cluster with I-C(140) Fullerene Topology**

We report on an effective cluster expansion of CuBr-linked aggregates by the increase of the steric bulk of the Cp(R) ligand in the pentatopic molecules [Cp(R)Fe(η(5)-P(5))]. Using [Cp(BIG)Fe(η(5)-P(5))] (Cp(BIG)=C(5)(4-nBuC(6)H(4))(5)), the novel multishell aggregate [{Cp(BIG)Fe(η(5:2:1:1:1:1:1)-P(...

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Detalles Bibliográficos
Autores principales: Heinl, Sebastian, Peresypkina, Eugenia, Sutter, Jörg, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4691335/
https://www.ncbi.nlm.nih.gov/pubmed/26411255
http://dx.doi.org/10.1002/anie.201505516
Descripción
Sumario:We report on an effective cluster expansion of CuBr-linked aggregates by the increase of the steric bulk of the Cp(R) ligand in the pentatopic molecules [Cp(R)Fe(η(5)-P(5))]. Using [Cp(BIG)Fe(η(5)-P(5))] (Cp(BIG)=C(5)(4-nBuC(6)H(4))(5)), the novel multishell aggregate [{Cp(BIG)Fe(η(5:2:1:1:1:1:1)-P(5))}(12)(CuBr)(92)] is obtained. It shows topological analogy to the theoretically predicted I-C(140) fullerene molecule. The spherical cluster was comprehensively characterized by various methods in solution and in the solid state.

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