Giant Spherical Cluster with I-C(140) Fullerene Topology**

We report on an effective cluster expansion of CuBr-linked aggregates by the increase of the steric bulk of the Cp(R) ligand in the pentatopic molecules [Cp(R)Fe(η(5)-P(5))]. Using [Cp(BIG)Fe(η(5)-P(5))] (Cp(BIG)=C(5)(4-nBuC(6)H(4))(5)), the novel multishell aggregate [{Cp(BIG)Fe(η(5:2:1:1:1:1:1)-P(...

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Detalles Bibliográficos
Autores principales: Heinl, Sebastian, Peresypkina, Eugenia, Sutter, Jörg, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4691335/
https://www.ncbi.nlm.nih.gov/pubmed/26411255
http://dx.doi.org/10.1002/anie.201505516
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author Heinl, Sebastian
Peresypkina, Eugenia
Sutter, Jörg
Scheer, Manfred
author_facet Heinl, Sebastian
Peresypkina, Eugenia
Sutter, Jörg
Scheer, Manfred
author_sort Heinl, Sebastian
collection PubMed
description We report on an effective cluster expansion of CuBr-linked aggregates by the increase of the steric bulk of the Cp(R) ligand in the pentatopic molecules [Cp(R)Fe(η(5)-P(5))]. Using [Cp(BIG)Fe(η(5)-P(5))] (Cp(BIG)=C(5)(4-nBuC(6)H(4))(5)), the novel multishell aggregate [{Cp(BIG)Fe(η(5:2:1:1:1:1:1)-P(5))}(12)(CuBr)(92)] is obtained. It shows topological analogy to the theoretically predicted I-C(140) fullerene molecule. The spherical cluster was comprehensively characterized by various methods in solution and in the solid state.
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spelling pubmed-46913352015-12-31 Giant Spherical Cluster with I-C(140) Fullerene Topology** Heinl, Sebastian Peresypkina, Eugenia Sutter, Jörg Scheer, Manfred Angew Chem Int Ed Engl Communications We report on an effective cluster expansion of CuBr-linked aggregates by the increase of the steric bulk of the Cp(R) ligand in the pentatopic molecules [Cp(R)Fe(η(5)-P(5))]. Using [Cp(BIG)Fe(η(5)-P(5))] (Cp(BIG)=C(5)(4-nBuC(6)H(4))(5)), the novel multishell aggregate [{Cp(BIG)Fe(η(5:2:1:1:1:1:1)-P(5))}(12)(CuBr)(92)] is obtained. It shows topological analogy to the theoretically predicted I-C(140) fullerene molecule. The spherical cluster was comprehensively characterized by various methods in solution and in the solid state. WILEY-VCH Verlag 2015-11-02 2015-09-28 /pmc/articles/PMC4691335/ /pubmed/26411255 http://dx.doi.org/10.1002/anie.201505516 Text en © 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of Creative Commons Attribution NonCommercial-NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made. https://creativecommons.org/licenses/by/4.0/ © 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of Creative Commons Attribution NonCommercial-NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.
spellingShingle Communications
Heinl, Sebastian
Peresypkina, Eugenia
Sutter, Jörg
Scheer, Manfred
Giant Spherical Cluster with I-C(140) Fullerene Topology**
title Giant Spherical Cluster with I-C(140) Fullerene Topology**
title_full Giant Spherical Cluster with I-C(140) Fullerene Topology**
title_fullStr Giant Spherical Cluster with I-C(140) Fullerene Topology**
title_full_unstemmed Giant Spherical Cluster with I-C(140) Fullerene Topology**
title_short Giant Spherical Cluster with I-C(140) Fullerene Topology**
title_sort giant spherical cluster with i-c(140) fullerene topology**
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4691335/
https://www.ncbi.nlm.nih.gov/pubmed/26411255
http://dx.doi.org/10.1002/anie.201505516
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