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Efficiency Enhancement of Cocktail Dye of Ixora coccinea and Tradescantia spathacea in DSSC
The use of anthocyanin dyes extracted from epidermal leaves of Tradescantia spathacea (Trant) and petals of Ixora coccinea (IX) was evaluated in the application of dye-sensitized solar cells (DSSCs). Subsequently, cocktail anthocyanin dyes from these dyes were prepared and how they enhanced the cell...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Hindawi Publishing Corporation
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4697096/ https://www.ncbi.nlm.nih.gov/pubmed/26793239 http://dx.doi.org/10.1155/2015/582091 |
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author | Zolkepli, Zularif Lim, Andery Ekanayake, Piyasiri Tennakoon, Kushan |
author_facet | Zolkepli, Zularif Lim, Andery Ekanayake, Piyasiri Tennakoon, Kushan |
author_sort | Zolkepli, Zularif |
collection | PubMed |
description | The use of anthocyanin dyes extracted from epidermal leaves of Tradescantia spathacea (Trant) and petals of Ixora coccinea (IX) was evaluated in the application of dye-sensitized solar cells (DSSCs). Subsequently, cocktail anthocyanin dyes from these dyes were prepared and how they enhanced the cell's overall performance was assessed using five different volume-to-volume ratios. Cocktail dyes absorbed a wider range of light in the visible region, thus increasing the cell efficiencies of the cocktail dyes when compared to the DSSC sensitized by individual dyes. The surface charge (zeta-potential), average size of aggregated anthocyanin molecules (zetasizer), and anthocyanin stability in different storage temperatures were analyzed and recorded. Lower size of aggregated dye molecules as revealed from the cocktail dyes ensured better adsorption onto the TiO(2) film. Tradescantia/Ixora pigments mixed in 1 : 4 ratio showed the highest cell efficiency of η = 0.80%, under the irradiance of 100 mW cm(−2), with a short-circuit current density 4.185 mA/cm(2), open-circuit voltage of 0.346 V, and fill factor of 0.499. It was found that the desired storage temperature for these cocktail dyes to be stable over time was −20°C, in which the anthocyanin half-life was about approximately 1727 days. |
format | Online Article Text |
id | pubmed-4697096 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | Hindawi Publishing Corporation |
record_format | MEDLINE/PubMed |
spelling | pubmed-46970962016-01-20 Efficiency Enhancement of Cocktail Dye of Ixora coccinea and Tradescantia spathacea in DSSC Zolkepli, Zularif Lim, Andery Ekanayake, Piyasiri Tennakoon, Kushan J Biophys Research Article The use of anthocyanin dyes extracted from epidermal leaves of Tradescantia spathacea (Trant) and petals of Ixora coccinea (IX) was evaluated in the application of dye-sensitized solar cells (DSSCs). Subsequently, cocktail anthocyanin dyes from these dyes were prepared and how they enhanced the cell's overall performance was assessed using five different volume-to-volume ratios. Cocktail dyes absorbed a wider range of light in the visible region, thus increasing the cell efficiencies of the cocktail dyes when compared to the DSSC sensitized by individual dyes. The surface charge (zeta-potential), average size of aggregated anthocyanin molecules (zetasizer), and anthocyanin stability in different storage temperatures were analyzed and recorded. Lower size of aggregated dye molecules as revealed from the cocktail dyes ensured better adsorption onto the TiO(2) film. Tradescantia/Ixora pigments mixed in 1 : 4 ratio showed the highest cell efficiency of η = 0.80%, under the irradiance of 100 mW cm(−2), with a short-circuit current density 4.185 mA/cm(2), open-circuit voltage of 0.346 V, and fill factor of 0.499. It was found that the desired storage temperature for these cocktail dyes to be stable over time was −20°C, in which the anthocyanin half-life was about approximately 1727 days. Hindawi Publishing Corporation 2015 2015-12-17 /pmc/articles/PMC4697096/ /pubmed/26793239 http://dx.doi.org/10.1155/2015/582091 Text en Copyright © 2015 Zularif Zolkepli et al. https://creativecommons.org/licenses/by/4.0/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Research Article Zolkepli, Zularif Lim, Andery Ekanayake, Piyasiri Tennakoon, Kushan Efficiency Enhancement of Cocktail Dye of Ixora coccinea and Tradescantia spathacea in DSSC |
title | Efficiency Enhancement of Cocktail Dye of Ixora coccinea and Tradescantia spathacea in DSSC |
title_full | Efficiency Enhancement of Cocktail Dye of Ixora coccinea and Tradescantia spathacea in DSSC |
title_fullStr | Efficiency Enhancement of Cocktail Dye of Ixora coccinea and Tradescantia spathacea in DSSC |
title_full_unstemmed | Efficiency Enhancement of Cocktail Dye of Ixora coccinea and Tradescantia spathacea in DSSC |
title_short | Efficiency Enhancement of Cocktail Dye of Ixora coccinea and Tradescantia spathacea in DSSC |
title_sort | efficiency enhancement of cocktail dye of ixora coccinea and tradescantia spathacea in dssc |
topic | Research Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4697096/ https://www.ncbi.nlm.nih.gov/pubmed/26793239 http://dx.doi.org/10.1155/2015/582091 |
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