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Efficiency Enhancement of Cocktail Dye of Ixora coccinea and Tradescantia spathacea in DSSC

The use of anthocyanin dyes extracted from epidermal leaves of Tradescantia spathacea (Trant) and petals of Ixora coccinea (IX) was evaluated in the application of dye-sensitized solar cells (DSSCs). Subsequently, cocktail anthocyanin dyes from these dyes were prepared and how they enhanced the cell...

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Autores principales: Zolkepli, Zularif, Lim, Andery, Ekanayake, Piyasiri, Tennakoon, Kushan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Hindawi Publishing Corporation 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4697096/
https://www.ncbi.nlm.nih.gov/pubmed/26793239
http://dx.doi.org/10.1155/2015/582091
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author Zolkepli, Zularif
Lim, Andery
Ekanayake, Piyasiri
Tennakoon, Kushan
author_facet Zolkepli, Zularif
Lim, Andery
Ekanayake, Piyasiri
Tennakoon, Kushan
author_sort Zolkepli, Zularif
collection PubMed
description The use of anthocyanin dyes extracted from epidermal leaves of Tradescantia spathacea (Trant) and petals of Ixora coccinea (IX) was evaluated in the application of dye-sensitized solar cells (DSSCs). Subsequently, cocktail anthocyanin dyes from these dyes were prepared and how they enhanced the cell's overall performance was assessed using five different volume-to-volume ratios. Cocktail dyes absorbed a wider range of light in the visible region, thus increasing the cell efficiencies of the cocktail dyes when compared to the DSSC sensitized by individual dyes. The surface charge (zeta-potential), average size of aggregated anthocyanin molecules (zetasizer), and anthocyanin stability in different storage temperatures were analyzed and recorded. Lower size of aggregated dye molecules as revealed from the cocktail dyes ensured better adsorption onto the TiO(2) film. Tradescantia/Ixora pigments mixed in 1 : 4 ratio showed the highest cell efficiency of η = 0.80%, under the irradiance of 100 mW cm(−2), with a short-circuit current density 4.185 mA/cm(2), open-circuit voltage of 0.346 V, and fill factor of 0.499. It was found that the desired storage temperature for these cocktail dyes to be stable over time was −20°C, in which the anthocyanin half-life was about approximately 1727 days.
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spelling pubmed-46970962016-01-20 Efficiency Enhancement of Cocktail Dye of Ixora coccinea and Tradescantia spathacea in DSSC Zolkepli, Zularif Lim, Andery Ekanayake, Piyasiri Tennakoon, Kushan J Biophys Research Article The use of anthocyanin dyes extracted from epidermal leaves of Tradescantia spathacea (Trant) and petals of Ixora coccinea (IX) was evaluated in the application of dye-sensitized solar cells (DSSCs). Subsequently, cocktail anthocyanin dyes from these dyes were prepared and how they enhanced the cell's overall performance was assessed using five different volume-to-volume ratios. Cocktail dyes absorbed a wider range of light in the visible region, thus increasing the cell efficiencies of the cocktail dyes when compared to the DSSC sensitized by individual dyes. The surface charge (zeta-potential), average size of aggregated anthocyanin molecules (zetasizer), and anthocyanin stability in different storage temperatures were analyzed and recorded. Lower size of aggregated dye molecules as revealed from the cocktail dyes ensured better adsorption onto the TiO(2) film. Tradescantia/Ixora pigments mixed in 1 : 4 ratio showed the highest cell efficiency of η = 0.80%, under the irradiance of 100 mW cm(−2), with a short-circuit current density 4.185 mA/cm(2), open-circuit voltage of 0.346 V, and fill factor of 0.499. It was found that the desired storage temperature for these cocktail dyes to be stable over time was −20°C, in which the anthocyanin half-life was about approximately 1727 days. Hindawi Publishing Corporation 2015 2015-12-17 /pmc/articles/PMC4697096/ /pubmed/26793239 http://dx.doi.org/10.1155/2015/582091 Text en Copyright © 2015 Zularif Zolkepli et al. https://creativecommons.org/licenses/by/4.0/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Article
Zolkepli, Zularif
Lim, Andery
Ekanayake, Piyasiri
Tennakoon, Kushan
Efficiency Enhancement of Cocktail Dye of Ixora coccinea and Tradescantia spathacea in DSSC
title Efficiency Enhancement of Cocktail Dye of Ixora coccinea and Tradescantia spathacea in DSSC
title_full Efficiency Enhancement of Cocktail Dye of Ixora coccinea and Tradescantia spathacea in DSSC
title_fullStr Efficiency Enhancement of Cocktail Dye of Ixora coccinea and Tradescantia spathacea in DSSC
title_full_unstemmed Efficiency Enhancement of Cocktail Dye of Ixora coccinea and Tradescantia spathacea in DSSC
title_short Efficiency Enhancement of Cocktail Dye of Ixora coccinea and Tradescantia spathacea in DSSC
title_sort efficiency enhancement of cocktail dye of ixora coccinea and tradescantia spathacea in dssc
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4697096/
https://www.ncbi.nlm.nih.gov/pubmed/26793239
http://dx.doi.org/10.1155/2015/582091
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