Crystal structure of aqua­bis­(hepta­fluoro­butano­ato-κO)(1,10′-phenanthroline-κ(2) N,N′)copper(II)

The title compound, [Cu(C(4)F(7)O(2))(2)(C(12)H(8)N(2))(H(2)O)], is mononuclear and contains a penta­coordinated Cu(II) ion. The geometry of Cu(II) ion can be described as distorted square-pyramidal with two O atoms of two butano­ate anions and two N atoms of the o-phenanthroline ligand occupying th...

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Detalles Bibliográficos
Autor principal: Kani, Ibrahim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4704741/
https://www.ncbi.nlm.nih.gov/pubmed/26870573
http://dx.doi.org/10.1107/S2056989015022720
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author Kani, Ibrahim
author_facet Kani, Ibrahim
author_sort Kani, Ibrahim
collection PubMed
description The title compound, [Cu(C(4)F(7)O(2))(2)(C(12)H(8)N(2))(H(2)O)], is mononuclear and contains a penta­coordinated Cu(II) ion. The geometry of Cu(II) ion can be described as distorted square-pyramidal with two O atoms of two butano­ate anions and two N atoms of the o-phenanthroline ligand occupying the basal plane, and a water O atom located at the axial position. In the crystal, C—H⋯(O,F) and O—H⋯(O,F) hydrogen bonds and π–π inter­actions [centroid-to-centroid distance 3.533 (2) Å] link the mol­ecules into a three-dimensional supra­molecular structure.
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spelling pubmed-47047412016-02-11 Crystal structure of aqua­bis­(hepta­fluoro­butano­ato-κO)(1,10′-phenanthroline-κ(2) N,N′)copper(II) Kani, Ibrahim Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [Cu(C(4)F(7)O(2))(2)(C(12)H(8)N(2))(H(2)O)], is mononuclear and contains a penta­coordinated Cu(II) ion. The geometry of Cu(II) ion can be described as distorted square-pyramidal with two O atoms of two butano­ate anions and two N atoms of the o-phenanthroline ligand occupying the basal plane, and a water O atom located at the axial position. In the crystal, C—H⋯(O,F) and O—H⋯(O,F) hydrogen bonds and π–π inter­actions [centroid-to-centroid distance 3.533 (2) Å] link the mol­ecules into a three-dimensional supra­molecular structure. International Union of Crystallography 2016-01-01 /pmc/articles/PMC4704741/ /pubmed/26870573 http://dx.doi.org/10.1107/S2056989015022720 Text en © Ibrahim Kani 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Kani, Ibrahim
Crystal structure of aqua­bis­(hepta­fluoro­butano­ato-κO)(1,10′-phenanthroline-κ(2) N,N′)copper(II)
title Crystal structure of aqua­bis­(hepta­fluoro­butano­ato-κO)(1,10′-phenanthroline-κ(2) N,N′)copper(II)
title_full Crystal structure of aqua­bis­(hepta­fluoro­butano­ato-κO)(1,10′-phenanthroline-κ(2) N,N′)copper(II)
title_fullStr Crystal structure of aqua­bis­(hepta­fluoro­butano­ato-κO)(1,10′-phenanthroline-κ(2) N,N′)copper(II)
title_full_unstemmed Crystal structure of aqua­bis­(hepta­fluoro­butano­ato-κO)(1,10′-phenanthroline-κ(2) N,N′)copper(II)
title_short Crystal structure of aqua­bis­(hepta­fluoro­butano­ato-κO)(1,10′-phenanthroline-κ(2) N,N′)copper(II)
title_sort crystal structure of aqua­bis­(hepta­fluoro­butano­ato-κo)(1,10′-phenanthroline-κ(2) n,n′)copper(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4704741/
https://www.ncbi.nlm.nih.gov/pubmed/26870573
http://dx.doi.org/10.1107/S2056989015022720
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