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Crystal structure of N-{4-[(6-chloro­pyridin-3-yl)meth­oxy]phen­yl}-2,6-di­fluoro­benzamide

In the title compound, C(19)H(13)ClF(2)N(2)O(2), the conformation of the N—H bond in the amide segment is anti to the C=O bond. The mol­ecule is not planar, with dihedral angles between the central benzene ring and the outer benzene and pyridyl rings of 73.35 (7) and 81.26 (6)°, respectively. A weak...

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Detalles Bibliográficos
Autores principales: Liang, Ying, Shi, Li-Qiao, Yang, Zi-Wen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4704742/
https://www.ncbi.nlm.nih.gov/pubmed/26870586
http://dx.doi.org/10.1107/S2056989015023701
Descripción
Sumario:In the title compound, C(19)H(13)ClF(2)N(2)O(2), the conformation of the N—H bond in the amide segment is anti to the C=O bond. The mol­ecule is not planar, with dihedral angles between the central benzene ring and the outer benzene and pyridyl rings of 73.35 (7) and 81.26 (6)°, respectively. A weak intra­molecular C—H⋯O hydrogen bond occurs. In the crystal, N—H⋯N, C—H⋯O and C—H⋯F hydrogen bonds lead to the formation of dimers. The N—H⋯N inversion dimers are linked by π–π contacts between adjacent pyridine rings [centroid–centroid = 3.8541 (12) Å] and C—H⋯π inter­actions. These contacts combine to stack the mol­ecules along the a axis.