Crystal structure of catena-poly[N,N,N′,N′-tetra­methyl­guanidinium [(chlorido­cadmate)-di-μ-chlorido]]

In the structure of the title salt, {(C(5)H(14)N(3))[CdCl(3)]}(n), the Cd(II) atom of the complex anion is five-coordinated by one terminal and four bridging Cl atoms. The corresponding coordination polyhedron is a distorted trigonal bipyramid, with Cd—Cl distances in the range 2.4829 (4)–2.6402 (4)...

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Autores principales: Ndiaye, Mamadou, Samb, Abdoulaye, Diop, Libasse, Maris, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4704744/
https://www.ncbi.nlm.nih.gov/pubmed/26870572
http://dx.doi.org/10.1107/S2056989015020836
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author Ndiaye, Mamadou
Samb, Abdoulaye
Diop, Libasse
Maris, Thierry
author_facet Ndiaye, Mamadou
Samb, Abdoulaye
Diop, Libasse
Maris, Thierry
author_sort Ndiaye, Mamadou
collection PubMed
description In the structure of the title salt, {(C(5)H(14)N(3))[CdCl(3)]}(n), the Cd(II) atom of the complex anion is five-coordinated by one terminal and four bridging Cl atoms. The corresponding coordination polyhedron is a distorted trigonal bipyramid, with Cd—Cl distances in the range 2.4829 (4)–2.6402 (4) Å. The bipyramids are condensed into a polyanionic zigzag chain extending parallel to [101]. The tetra­methyl­guanidinium cations are situated between the polyanionic chains and are linked to them through N—H⋯Cl hydrogen bonds, forming a layered network parallel to (010).
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spelling pubmed-47047442016-02-11 Crystal structure of catena-poly[N,N,N′,N′-tetra­methyl­guanidinium [(chlorido­cadmate)-di-μ-chlorido]] Ndiaye, Mamadou Samb, Abdoulaye Diop, Libasse Maris, Thierry Acta Crystallogr E Crystallogr Commun Research Communications In the structure of the title salt, {(C(5)H(14)N(3))[CdCl(3)]}(n), the Cd(II) atom of the complex anion is five-coordinated by one terminal and four bridging Cl atoms. The corresponding coordination polyhedron is a distorted trigonal bipyramid, with Cd—Cl distances in the range 2.4829 (4)–2.6402 (4) Å. The bipyramids are condensed into a polyanionic zigzag chain extending parallel to [101]. The tetra­methyl­guanidinium cations are situated between the polyanionic chains and are linked to them through N—H⋯Cl hydrogen bonds, forming a layered network parallel to (010). International Union of Crystallography 2016-01-01 /pmc/articles/PMC4704744/ /pubmed/26870572 http://dx.doi.org/10.1107/S2056989015020836 Text en © Ndiaye et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Ndiaye, Mamadou
Samb, Abdoulaye
Diop, Libasse
Maris, Thierry
Crystal structure of catena-poly[N,N,N′,N′-tetra­methyl­guanidinium [(chlorido­cadmate)-di-μ-chlorido]]
title Crystal structure of catena-poly[N,N,N′,N′-tetra­methyl­guanidinium [(chlorido­cadmate)-di-μ-chlorido]]
title_full Crystal structure of catena-poly[N,N,N′,N′-tetra­methyl­guanidinium [(chlorido­cadmate)-di-μ-chlorido]]
title_fullStr Crystal structure of catena-poly[N,N,N′,N′-tetra­methyl­guanidinium [(chlorido­cadmate)-di-μ-chlorido]]
title_full_unstemmed Crystal structure of catena-poly[N,N,N′,N′-tetra­methyl­guanidinium [(chlorido­cadmate)-di-μ-chlorido]]
title_short Crystal structure of catena-poly[N,N,N′,N′-tetra­methyl­guanidinium [(chlorido­cadmate)-di-μ-chlorido]]
title_sort crystal structure of catena-poly[n,n,n′,n′-tetra­methyl­guanidinium [(chlorido­cadmate)-di-μ-chlorido]]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4704744/
https://www.ncbi.nlm.nih.gov/pubmed/26870572
http://dx.doi.org/10.1107/S2056989015020836
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