Crystal structure of ethyl (1RS,6SR)-4-(2-methyl-1H-imidazol-4-yl)-2-oxo-6-(2,3,5-tri­chloro­phen­yl)cyclo­hex-3-ene-1-carboxyl­ate

The title compound, C(19)H(17)Cl(3)N(2)O(3), has been prepared in a cyclo­condensation reaction between 2,3,5-tri­chloro­benzaldehye and 4-acetyl-2-methyl-1H-imidazole. The cyclo­hexenone ring adopts an envelope conformation with the C atom substituted by the tri­chloro­phenyl ring as the flap. The...

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Autores principales: Mohan, Billava J., Sarojini, Balladka K., Yathirajan, Hemmige S., Rathore, Ravindranath, Glidewell, Christopher
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4704750/
https://www.ncbi.nlm.nih.gov/pubmed/26870579
http://dx.doi.org/10.1107/S2056989015023245
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author Mohan, Billava J.
Sarojini, Balladka K.
Yathirajan, Hemmige S.
Rathore, Ravindranath
Glidewell, Christopher
author_facet Mohan, Billava J.
Sarojini, Balladka K.
Yathirajan, Hemmige S.
Rathore, Ravindranath
Glidewell, Christopher
author_sort Mohan, Billava J.
collection PubMed
description The title compound, C(19)H(17)Cl(3)N(2)O(3), has been prepared in a cyclo­condensation reaction between 2,3,5-tri­chloro­benzaldehye and 4-acetyl-2-methyl-1H-imidazole. The cyclo­hexenone ring adopts an envelope conformation with the C atom substituted by the tri­chloro­phenyl ring as the flap. The mutually trans ester and aryl substituents both occupy equatorial sites. In the crystal, a combination of N—H⋯O and C—H⋯N hydrogen bonds links the mol­ecules into ribbons of edge-fused centrosymmetric rings, which enclose R (2) (2)(14) and R (4) (4)(16) alternate ring motifs, propagating along the b-axis direction.
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spelling pubmed-47047502016-02-11 Crystal structure of ethyl (1RS,6SR)-4-(2-methyl-1H-imidazol-4-yl)-2-oxo-6-(2,3,5-tri­chloro­phen­yl)cyclo­hex-3-ene-1-carboxyl­ate Mohan, Billava J. Sarojini, Balladka K. Yathirajan, Hemmige S. Rathore, Ravindranath Glidewell, Christopher Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(19)H(17)Cl(3)N(2)O(3), has been prepared in a cyclo­condensation reaction between 2,3,5-tri­chloro­benzaldehye and 4-acetyl-2-methyl-1H-imidazole. The cyclo­hexenone ring adopts an envelope conformation with the C atom substituted by the tri­chloro­phenyl ring as the flap. The mutually trans ester and aryl substituents both occupy equatorial sites. In the crystal, a combination of N—H⋯O and C—H⋯N hydrogen bonds links the mol­ecules into ribbons of edge-fused centrosymmetric rings, which enclose R (2) (2)(14) and R (4) (4)(16) alternate ring motifs, propagating along the b-axis direction. International Union of Crystallography 2016-01-01 /pmc/articles/PMC4704750/ /pubmed/26870579 http://dx.doi.org/10.1107/S2056989015023245 Text en © Mohan et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Mohan, Billava J.
Sarojini, Balladka K.
Yathirajan, Hemmige S.
Rathore, Ravindranath
Glidewell, Christopher
Crystal structure of ethyl (1RS,6SR)-4-(2-methyl-1H-imidazol-4-yl)-2-oxo-6-(2,3,5-tri­chloro­phen­yl)cyclo­hex-3-ene-1-carboxyl­ate
title Crystal structure of ethyl (1RS,6SR)-4-(2-methyl-1H-imidazol-4-yl)-2-oxo-6-(2,3,5-tri­chloro­phen­yl)cyclo­hex-3-ene-1-carboxyl­ate
title_full Crystal structure of ethyl (1RS,6SR)-4-(2-methyl-1H-imidazol-4-yl)-2-oxo-6-(2,3,5-tri­chloro­phen­yl)cyclo­hex-3-ene-1-carboxyl­ate
title_fullStr Crystal structure of ethyl (1RS,6SR)-4-(2-methyl-1H-imidazol-4-yl)-2-oxo-6-(2,3,5-tri­chloro­phen­yl)cyclo­hex-3-ene-1-carboxyl­ate
title_full_unstemmed Crystal structure of ethyl (1RS,6SR)-4-(2-methyl-1H-imidazol-4-yl)-2-oxo-6-(2,3,5-tri­chloro­phen­yl)cyclo­hex-3-ene-1-carboxyl­ate
title_short Crystal structure of ethyl (1RS,6SR)-4-(2-methyl-1H-imidazol-4-yl)-2-oxo-6-(2,3,5-tri­chloro­phen­yl)cyclo­hex-3-ene-1-carboxyl­ate
title_sort crystal structure of ethyl (1rs,6sr)-4-(2-methyl-1h-imidazol-4-yl)-2-oxo-6-(2,3,5-tri­chloro­phen­yl)cyclo­hex-3-ene-1-carboxyl­ate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4704750/
https://www.ncbi.nlm.nih.gov/pubmed/26870579
http://dx.doi.org/10.1107/S2056989015023245
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AT rathoreravindranath crystalstructureofethyl1rs6sr42methyl1himidazol4yl2oxo6235trichlorophenylcyclohex3ene1carboxylate
AT glidewellchristopher crystalstructureofethyl1rs6sr42methyl1himidazol4yl2oxo6235trichlorophenylcyclohex3ene1carboxylate

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