Crystal structure of tris­(di­methyl­amido-κN)­bis­(di­methyl­amine-κN)­zirconium(IV) iodide

Zirconium amides have become increasingly popular and useful due to their widespread use as precursors to other zirconium complexes and their use in the production of solid oxide fuel cells (SOFCs). Herein we report the mol­ecular structure of tris­(di­methyl­amido)­bis­(di­methyl­amine)­zirconium(I...

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Autores principales: Clark, Wesley D., Akurathi, Gopalakrishna, Valle, Henry U., Hollis, T. Keith
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4704753/
https://www.ncbi.nlm.nih.gov/pubmed/26870590
http://dx.doi.org/10.1107/S2056989015023919
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author Clark, Wesley D.
Akurathi, Gopalakrishna
Valle, Henry U.
Hollis, T. Keith
author_facet Clark, Wesley D.
Akurathi, Gopalakrishna
Valle, Henry U.
Hollis, T. Keith
author_sort Clark, Wesley D.
collection PubMed
description Zirconium amides have become increasingly popular and useful due to their widespread use as precursors to other zirconium complexes and their use in the production of solid oxide fuel cells (SOFCs). Herein we report the mol­ecular structure of tris­(di­methyl­amido)­bis­(di­methyl­amine)­zirconium(IV) iodide, [Zr(C(2)H(6)N)(3)(C(2)H(7)N)(2)]I. The bond lengths and bond angles are consistent with a slightly distorted trigonal–bipyramidal coordination geometry around the metal atom. N⋯I contacts of 3.6153 (15) and 3.5922 (14) Å are consistent with the presence of N—H⋯I inter­actions. These N—H⋯I inter­actions link the complex cations and iodide anions into extended chains that propagate parallel to the a axis.
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spelling pubmed-47047532016-02-11 Crystal structure of tris­(di­methyl­amido-κN)­bis­(di­methyl­amine-κN)­zirconium(IV) iodide Clark, Wesley D. Akurathi, Gopalakrishna Valle, Henry U. Hollis, T. Keith Acta Crystallogr E Crystallogr Commun Research Communications Zirconium amides have become increasingly popular and useful due to their widespread use as precursors to other zirconium complexes and their use in the production of solid oxide fuel cells (SOFCs). Herein we report the mol­ecular structure of tris­(di­methyl­amido)­bis­(di­methyl­amine)­zirconium(IV) iodide, [Zr(C(2)H(6)N)(3)(C(2)H(7)N)(2)]I. The bond lengths and bond angles are consistent with a slightly distorted trigonal–bipyramidal coordination geometry around the metal atom. N⋯I contacts of 3.6153 (15) and 3.5922 (14) Å are consistent with the presence of N—H⋯I inter­actions. These N—H⋯I inter­actions link the complex cations and iodide anions into extended chains that propagate parallel to the a axis. International Union of Crystallography 2016-01-01 /pmc/articles/PMC4704753/ /pubmed/26870590 http://dx.doi.org/10.1107/S2056989015023919 Text en © Clark et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Clark, Wesley D.
Akurathi, Gopalakrishna
Valle, Henry U.
Hollis, T. Keith
Crystal structure of tris­(di­methyl­amido-κN)­bis­(di­methyl­amine-κN)­zirconium(IV) iodide
title Crystal structure of tris­(di­methyl­amido-κN)­bis­(di­methyl­amine-κN)­zirconium(IV) iodide
title_full Crystal structure of tris­(di­methyl­amido-κN)­bis­(di­methyl­amine-κN)­zirconium(IV) iodide
title_fullStr Crystal structure of tris­(di­methyl­amido-κN)­bis­(di­methyl­amine-κN)­zirconium(IV) iodide
title_full_unstemmed Crystal structure of tris­(di­methyl­amido-κN)­bis­(di­methyl­amine-κN)­zirconium(IV) iodide
title_short Crystal structure of tris­(di­methyl­amido-κN)­bis­(di­methyl­amine-κN)­zirconium(IV) iodide
title_sort crystal structure of tris­(di­methyl­amido-κn)­bis­(di­methyl­amine-κn)­zirconium(iv) iodide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4704753/
https://www.ncbi.nlm.nih.gov/pubmed/26870590
http://dx.doi.org/10.1107/S2056989015023919
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AT vallehenryu crystalstructureoftrisdimethylamidoknbisdimethylamineknzirconiumiviodide
AT hollistkeith crystalstructureoftrisdimethylamidoknbisdimethylamineknzirconiumiviodide

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