Crystal structure of 3-ferrocenyl-1-phenyl-1H-pyrrole, [Fe(η(5)-C(5)H(4) (c)C(4)H(3) NPh)(η(5)-C(5)H(5))]

The mol­ecular structure of the title compound, [Fe(C(5)H(5))(C(15)H(12)N)], consists of a ferrocene moiety with an N-phenyl­pyrrole heterocycle bound to one cyclo­penta­dienyl ring. The 1,3-disubstitution of the pyrrole results in an L-shaped arrangement of the mol­ecule with plane inter­sections o...

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Detalles Bibliográficos
Autores principales: Pfaff, Ulrike, Korb, Marcus, Lang, Heinrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4704767/
https://www.ncbi.nlm.nih.gov/pubmed/26870594
http://dx.doi.org/10.1107/S2056989015024214
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author Pfaff, Ulrike
Korb, Marcus
Lang, Heinrich
author_facet Pfaff, Ulrike
Korb, Marcus
Lang, Heinrich
author_sort Pfaff, Ulrike
collection PubMed
description The mol­ecular structure of the title compound, [Fe(C(5)H(5))(C(15)H(12)N)], consists of a ferrocene moiety with an N-phenyl­pyrrole heterocycle bound to one cyclo­penta­dienyl ring. The 1,3-disubstitution of the pyrrole results in an L-shaped arrangement of the mol­ecule with plane inter­sections of 2.78 (17)° between the pyrrole and the N-bonded phenyl ring and of 8.17 (18)° between the pyrrole and the cyclo­penta­dienyl ring. In the crystal, no remarkable inter­molecular inter­actions are observed
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spelling pubmed-47047672016-02-11 Crystal structure of 3-ferrocenyl-1-phenyl-1H-pyrrole, [Fe(η(5)-C(5)H(4) (c)C(4)H(3) NPh)(η(5)-C(5)H(5))] Pfaff, Ulrike Korb, Marcus Lang, Heinrich Acta Crystallogr E Crystallogr Commun Research Communications The mol­ecular structure of the title compound, [Fe(C(5)H(5))(C(15)H(12)N)], consists of a ferrocene moiety with an N-phenyl­pyrrole heterocycle bound to one cyclo­penta­dienyl ring. The 1,3-disubstitution of the pyrrole results in an L-shaped arrangement of the mol­ecule with plane inter­sections of 2.78 (17)° between the pyrrole and the N-bonded phenyl ring and of 8.17 (18)° between the pyrrole and the cyclo­penta­dienyl ring. In the crystal, no remarkable inter­molecular inter­actions are observed International Union of Crystallography 2016-01-01 /pmc/articles/PMC4704767/ /pubmed/26870594 http://dx.doi.org/10.1107/S2056989015024214 Text en © Pfaff et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Pfaff, Ulrike
Korb, Marcus
Lang, Heinrich
Crystal structure of 3-ferrocenyl-1-phenyl-1H-pyrrole, [Fe(η(5)-C(5)H(4) (c)C(4)H(3) NPh)(η(5)-C(5)H(5))]
title Crystal structure of 3-ferrocenyl-1-phenyl-1H-pyrrole, [Fe(η(5)-C(5)H(4) (c)C(4)H(3) NPh)(η(5)-C(5)H(5))]
title_full Crystal structure of 3-ferrocenyl-1-phenyl-1H-pyrrole, [Fe(η(5)-C(5)H(4) (c)C(4)H(3) NPh)(η(5)-C(5)H(5))]
title_fullStr Crystal structure of 3-ferrocenyl-1-phenyl-1H-pyrrole, [Fe(η(5)-C(5)H(4) (c)C(4)H(3) NPh)(η(5)-C(5)H(5))]
title_full_unstemmed Crystal structure of 3-ferrocenyl-1-phenyl-1H-pyrrole, [Fe(η(5)-C(5)H(4) (c)C(4)H(3) NPh)(η(5)-C(5)H(5))]
title_short Crystal structure of 3-ferrocenyl-1-phenyl-1H-pyrrole, [Fe(η(5)-C(5)H(4) (c)C(4)H(3) NPh)(η(5)-C(5)H(5))]
title_sort crystal structure of 3-ferrocenyl-1-phenyl-1h-pyrrole, [fe(η(5)-c(5)h(4) (c)c(4)h(3) nph)(η(5)-c(5)h(5))]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4704767/
https://www.ncbi.nlm.nih.gov/pubmed/26870594
http://dx.doi.org/10.1107/S2056989015024214
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AT langheinrich crystalstructureof3ferrocenyl1phenyl1hpyrrolefeē5c5h4cc4h3nphē5c5h5

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