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High Coke-Resistance Pt/Mg(1-x)Ni(x)O Catalyst for Dry Reforming of Methane
A highly active and stable nano structured Pt/Mg(1-x)Ni(x)O catalysts was developed by a simple co-precipitation method. The obtained Pt/Mg(1-x)Ni(x)O catalyst exhibited cubic structure nanocatalyst with a size of 50–80 nm and realized CH(4) and CO(2) conversions as high as 98% at 900°C with excelle...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Public Library of Science
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4706417/ https://www.ncbi.nlm.nih.gov/pubmed/26745623 http://dx.doi.org/10.1371/journal.pone.0145862 |
Sumario: | A highly active and stable nano structured Pt/Mg(1-x)Ni(x)O catalysts was developed by a simple co-precipitation method. The obtained Pt/Mg(1-x)Ni(x)O catalyst exhibited cubic structure nanocatalyst with a size of 50–80 nm and realized CH(4) and CO(2) conversions as high as 98% at 900°C with excellent stability in the dry reforming of methane. The characterization of catalyst was performed using various kinds of analytical techniques including XRD, BET, XRF, TPR-H(2), TGA, TEM, FESEM, FT-IR, and XPS analyses. Characterization of spent catalyst further confirms that Pt/Mg(1-x)Ni(x)O catalyst has high coke-resistance for dry reforming. Thus, the catalyst demonstrated in this study, offers a promising catalyst for resolving the dilemma between dispersion and reducibility of supported metal, as well as activity and stability during high temperature reactions. |
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