Characteristics of ammonia, acid gases, and PM(2.5) for three typical land-use types in the North China Plain

Air pollution is one of the most serious environmental problems in China due to its rapid economic development alongside a very large consumption of fossil fuel, particularly in the North China Plain (NCP). During the period 2011–2014, we integrated active and passive sampling methods to perform continuous measurements of NH(3), HNO(3), NO(2), and PM(2.5) at two urban, one suburban, and two rural sites in the NCP. The annual average concentrations of NH(3), NO(2), and HNO(3) across the five sites were in the ranges 8.5–23.0, 22.2–50.5, and 5.5–9.7 μg m(−3), respectively, showing no significant spatial differences for NH(3) and HNO(3) but significantly higher NO(2) concentration at the urban sites. At each site, annual average concentrations of NH(3) and NO(2) showed increasing and decreasing trends, respectively, while there was no obvious trend in annual HNO(3) concentrations. Daily PM(2.5) concentrations ranged from 11.8 to 621.0 μg m(−3) at the urban site, from 19.8 to 692.9 μg m(−3) at the suburban site, and from 23.9 to 754.5 μg m(−3) at the two rural sites, with more than 70 % of sampling days exceeding 75 μg m(−3). Concentrations of water-soluble ions in PM(2.5) ranked differently between the non-rural and rural sites. The three dominant ions were NH(4)(+), NO(3)(−), and SO(4)(2−) and mainly existed as (NH(4))(2)SO(4), NH(4)HSO(4), and NH(4)NO(3), and their concentrations averaged 48.6 ± 44.9, 41.2 ± 40.8, and 49.6 ± 35.9 μg m(−3) at the urban, suburban, and rural sites, respectively. Ion balance calculations indicated that PM(2.5) was neutral at the non-rural sites but acidic at the rural sites. Seasonal variations of the gases and aerosols exhibited different patterns, depending on source emission strength and meteorological conditions. Our results suggest that a feasible pathway to control PM(2.5) pollution in the NCP should target ammonia and acid gases together. ELECTRONIC SUPPLEMENTARY MATERIAL: The online version of this article (doi:10.1007/s11356-015-5648-3) contains supplementary material, which is available to authorized users.