Crystal structure of nitridobis(tri­methyl­silanolato)[1,1,1-trimethyl-N-(tri­methyl­sil­yl)silanaminato]molybdenum(VI)

In the title compound, [Mo(C(6)H(18)NSi(2))(C(3)H(9)OSi)(2)N], the Mo(VI) cation is located on a mirror plane and is coordinated by a nitride anion, a 1,1,1-trimethyl-N-(tri­methyl­sil­yl)silanaminate anion and two tri­methyl­silanolate anions in a distorted tetra­hedral geometry; the N atom and two...

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Detalles Bibliográficos
Autores principales: Geng, Caiwei, Hao, Xiang, Jiao, Peng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719822/
https://www.ncbi.nlm.nih.gov/pubmed/26870413
http://dx.doi.org/10.1107/S2056989015021192
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author Geng, Caiwei
Hao, Xiang
Jiao, Peng
author_facet Geng, Caiwei
Hao, Xiang
Jiao, Peng
author_sort Geng, Caiwei
collection PubMed
description In the title compound, [Mo(C(6)H(18)NSi(2))(C(3)H(9)OSi)(2)N], the Mo(VI) cation is located on a mirror plane and is coordinated by a nitride anion, a 1,1,1-trimethyl-N-(tri­methyl­sil­yl)silanaminate anion and two tri­methyl­silanolate anions in a distorted tetra­hedral geometry; the N atom and two Si atoms of the 1,1,1-trimethyl-N-(tri­methyl­sil­yl)silanaminato anionic ligand are also located on the mirror plane. The Mo N bond length of 1.633 (6) Å is much shorter than the Mo—N single-bond length of 1.934 (7) Å. No hydrogen bonding is observed in the crystal structure.
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spelling pubmed-47198222016-02-11 Crystal structure of nitridobis(tri­methyl­silanolato)[1,1,1-trimethyl-N-(tri­methyl­sil­yl)silanaminato]molybdenum(VI) Geng, Caiwei Hao, Xiang Jiao, Peng Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Mo(C(6)H(18)NSi(2))(C(3)H(9)OSi)(2)N], the Mo(VI) cation is located on a mirror plane and is coordinated by a nitride anion, a 1,1,1-trimethyl-N-(tri­methyl­sil­yl)silanaminate anion and two tri­methyl­silanolate anions in a distorted tetra­hedral geometry; the N atom and two Si atoms of the 1,1,1-trimethyl-N-(tri­methyl­sil­yl)silanaminato anionic ligand are also located on the mirror plane. The Mo N bond length of 1.633 (6) Å is much shorter than the Mo—N single-bond length of 1.934 (7) Å. No hydrogen bonding is observed in the crystal structure. International Union of Crystallography 2015-11-14 /pmc/articles/PMC4719822/ /pubmed/26870413 http://dx.doi.org/10.1107/S2056989015021192 Text en © Geng et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Geng, Caiwei
Hao, Xiang
Jiao, Peng
Crystal structure of nitridobis(tri­methyl­silanolato)[1,1,1-trimethyl-N-(tri­methyl­sil­yl)silanaminato]molybdenum(VI)
title Crystal structure of nitridobis(tri­methyl­silanolato)[1,1,1-trimethyl-N-(tri­methyl­sil­yl)silanaminato]molybdenum(VI)
title_full Crystal structure of nitridobis(tri­methyl­silanolato)[1,1,1-trimethyl-N-(tri­methyl­sil­yl)silanaminato]molybdenum(VI)
title_fullStr Crystal structure of nitridobis(tri­methyl­silanolato)[1,1,1-trimethyl-N-(tri­methyl­sil­yl)silanaminato]molybdenum(VI)
title_full_unstemmed Crystal structure of nitridobis(tri­methyl­silanolato)[1,1,1-trimethyl-N-(tri­methyl­sil­yl)silanaminato]molybdenum(VI)
title_short Crystal structure of nitridobis(tri­methyl­silanolato)[1,1,1-trimethyl-N-(tri­methyl­sil­yl)silanaminato]molybdenum(VI)
title_sort crystal structure of nitridobis(tri­methyl­silanolato)[1,1,1-trimethyl-n-(tri­methyl­sil­yl)silanaminato]molybdenum(vi)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719822/
https://www.ncbi.nlm.nih.gov/pubmed/26870413
http://dx.doi.org/10.1107/S2056989015021192
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