Crystal structure of N-[(1S,2S)-2-amino­cyclo­hex­yl]-2,4,6-tri­methyl­benzene­sulfonamide

The title compound, C(15)H(24)N(2)O(2)S, was synthesized via a substitution reaction between the enanti­opure (1S,2S)-(+)-1,2-di­amino­cyclo­hexane and 2,4,6-tri­methyl­benzene-1-sulfonyl chloride. The cyclo­hexyl and phenyl substituents are oriented gauche around the sulfonamide S—N bond. In the cr...

Descripción completa

Detalles Bibliográficos
Autores principales: Ngassa, Felix N., Biros, Shannon M., Staples, Richard J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719828/
https://www.ncbi.nlm.nih.gov/pubmed/26870419
http://dx.doi.org/10.1107/S205698901502191X
_version_ 1782410982386040832
author Ngassa, Felix N.
Biros, Shannon M.
Staples, Richard J.
author_facet Ngassa, Felix N.
Biros, Shannon M.
Staples, Richard J.
author_sort Ngassa, Felix N.
collection PubMed
description The title compound, C(15)H(24)N(2)O(2)S, was synthesized via a substitution reaction between the enanti­opure (1S,2S)-(+)-1,2-di­amino­cyclo­hexane and 2,4,6-tri­methyl­benzene-1-sulfonyl chloride. The cyclo­hexyl and phenyl substituents are oriented gauche around the sulfonamide S—N bond. In the crystal, mol­ecules are linked via N—H⋯N hydrogen bonds, forming chains propagating along [100].
format Online
Article
Text
id pubmed-4719828
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-47198282016-02-11 Crystal structure of N-[(1S,2S)-2-amino­cyclo­hex­yl]-2,4,6-tri­methyl­benzene­sulfonamide Ngassa, Felix N. Biros, Shannon M. Staples, Richard J. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(15)H(24)N(2)O(2)S, was synthesized via a substitution reaction between the enanti­opure (1S,2S)-(+)-1,2-di­amino­cyclo­hexane and 2,4,6-tri­methyl­benzene-1-sulfonyl chloride. The cyclo­hexyl and phenyl substituents are oriented gauche around the sulfonamide S—N bond. In the crystal, mol­ecules are linked via N—H⋯N hydrogen bonds, forming chains propagating along [100]. International Union of Crystallography 2015-11-21 /pmc/articles/PMC4719828/ /pubmed/26870419 http://dx.doi.org/10.1107/S205698901502191X Text en © Ngassa et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Ngassa, Felix N.
Biros, Shannon M.
Staples, Richard J.
Crystal structure of N-[(1S,2S)-2-amino­cyclo­hex­yl]-2,4,6-tri­methyl­benzene­sulfonamide
title Crystal structure of N-[(1S,2S)-2-amino­cyclo­hex­yl]-2,4,6-tri­methyl­benzene­sulfonamide
title_full Crystal structure of N-[(1S,2S)-2-amino­cyclo­hex­yl]-2,4,6-tri­methyl­benzene­sulfonamide
title_fullStr Crystal structure of N-[(1S,2S)-2-amino­cyclo­hex­yl]-2,4,6-tri­methyl­benzene­sulfonamide
title_full_unstemmed Crystal structure of N-[(1S,2S)-2-amino­cyclo­hex­yl]-2,4,6-tri­methyl­benzene­sulfonamide
title_short Crystal structure of N-[(1S,2S)-2-amino­cyclo­hex­yl]-2,4,6-tri­methyl­benzene­sulfonamide
title_sort crystal structure of n-[(1s,2s)-2-amino­cyclo­hex­yl]-2,4,6-tri­methyl­benzene­sulfonamide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719828/
https://www.ncbi.nlm.nih.gov/pubmed/26870419
http://dx.doi.org/10.1107/S205698901502191X
work_keys_str_mv AT ngassafelixn crystalstructureofn1s2s2aminocyclohexyl246trimethylbenzenesulfonamide
AT birosshannonm crystalstructureofn1s2s2aminocyclohexyl246trimethylbenzenesulfonamide
AT staplesrichardj crystalstructureofn1s2s2aminocyclohexyl246trimethylbenzenesulfonamide

Ejemplares similares