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Crystal structure of 3-O-benzyl-4(R)-C-(1-benzyl-1H-1,2,3-triazol-4-yl)-1,2-O-iso­propyl­idene-α-d-erythro­furan­ose

The title compound, C(23)H(25)N(3)O(4), {systematic name: 1-benzyl-4-[(3aR,5R,6R,6aR)-6-benz­yloxy-2,2-di­methyl­tetra­hydro­furo[2,3-d][1,3]dioxol-5-yl]-1H-1,2,3-triazole}, consists of a substituted 2,2-di­methyl­tetra­hydro­furo[2,3-d][1,3]dioxole. The furan­ose ring adopts an envelope conformatio...

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Autores principales: Semjonovs, Nikita, Rjabovs, Vitalijs, Stepanovs, Dmitrijs, Turks, Maris
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719834/
https://www.ncbi.nlm.nih.gov/pubmed/26870425
http://dx.doi.org/10.1107/S2056989015022434
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author Semjonovs, Nikita
Rjabovs, Vitalijs
Stepanovs, Dmitrijs
Turks, Maris
author_facet Semjonovs, Nikita
Rjabovs, Vitalijs
Stepanovs, Dmitrijs
Turks, Maris
author_sort Semjonovs, Nikita
collection PubMed
description The title compound, C(23)H(25)N(3)O(4), {systematic name: 1-benzyl-4-[(3aR,5R,6R,6aR)-6-benz­yloxy-2,2-di­methyl­tetra­hydro­furo[2,3-d][1,3]dioxol-5-yl]-1H-1,2,3-triazole}, consists of a substituted 2,2-di­methyl­tetra­hydro­furo[2,3-d][1,3]dioxole. The furan­ose ring adopts an envelope conformation close to C (3)-exo, where the C atom substituted by the benz­yloxy group is the flap. The fused dioxolane ring also adopts an envelope conformation, with the methyl­ene C atom as the flap. In the crystal, mol­ecules are linked by weak C—H⋯O hydrogen bonds, forming zigzag chains along [010].
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spelling pubmed-47198342016-02-11 Crystal structure of 3-O-benzyl-4(R)-C-(1-benzyl-1H-1,2,3-triazol-4-yl)-1,2-O-iso­propyl­idene-α-d-erythro­furan­ose Semjonovs, Nikita Rjabovs, Vitalijs Stepanovs, Dmitrijs Turks, Maris Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(23)H(25)N(3)O(4), {systematic name: 1-benzyl-4-[(3aR,5R,6R,6aR)-6-benz­yloxy-2,2-di­methyl­tetra­hydro­furo[2,3-d][1,3]dioxol-5-yl]-1H-1,2,3-triazole}, consists of a substituted 2,2-di­methyl­tetra­hydro­furo[2,3-d][1,3]dioxole. The furan­ose ring adopts an envelope conformation close to C (3)-exo, where the C atom substituted by the benz­yloxy group is the flap. The fused dioxolane ring also adopts an envelope conformation, with the methyl­ene C atom as the flap. In the crystal, mol­ecules are linked by weak C—H⋯O hydrogen bonds, forming zigzag chains along [010]. International Union of Crystallography 2015-11-28 /pmc/articles/PMC4719834/ /pubmed/26870425 http://dx.doi.org/10.1107/S2056989015022434 Text en © Semjonovs et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Semjonovs, Nikita
Rjabovs, Vitalijs
Stepanovs, Dmitrijs
Turks, Maris
Crystal structure of 3-O-benzyl-4(R)-C-(1-benzyl-1H-1,2,3-triazol-4-yl)-1,2-O-iso­propyl­idene-α-d-erythro­furan­ose
title Crystal structure of 3-O-benzyl-4(R)-C-(1-benzyl-1H-1,2,3-triazol-4-yl)-1,2-O-iso­propyl­idene-α-d-erythro­furan­ose
title_full Crystal structure of 3-O-benzyl-4(R)-C-(1-benzyl-1H-1,2,3-triazol-4-yl)-1,2-O-iso­propyl­idene-α-d-erythro­furan­ose
title_fullStr Crystal structure of 3-O-benzyl-4(R)-C-(1-benzyl-1H-1,2,3-triazol-4-yl)-1,2-O-iso­propyl­idene-α-d-erythro­furan­ose
title_full_unstemmed Crystal structure of 3-O-benzyl-4(R)-C-(1-benzyl-1H-1,2,3-triazol-4-yl)-1,2-O-iso­propyl­idene-α-d-erythro­furan­ose
title_short Crystal structure of 3-O-benzyl-4(R)-C-(1-benzyl-1H-1,2,3-triazol-4-yl)-1,2-O-iso­propyl­idene-α-d-erythro­furan­ose
title_sort crystal structure of 3-o-benzyl-4(r)-c-(1-benzyl-1h-1,2,3-triazol-4-yl)-1,2-o-iso­propyl­idene-α-d-erythro­furan­ose
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719834/
https://www.ncbi.nlm.nih.gov/pubmed/26870425
http://dx.doi.org/10.1107/S2056989015022434
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