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Crystal structure of 3-O-benzyl-4(R)-C-(1-benzyl-1H-1,2,3-triazol-4-yl)-1,2-O-isopropylidene-α-d-erythrofuranose
The title compound, C(23)H(25)N(3)O(4), {systematic name: 1-benzyl-4-[(3aR,5R,6R,6aR)-6-benzyloxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl]-1H-1,2,3-triazole}, consists of a substituted 2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxole. The furanose ring adopts an envelope conformatio...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719834/ https://www.ncbi.nlm.nih.gov/pubmed/26870425 http://dx.doi.org/10.1107/S2056989015022434 |
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author | Semjonovs, Nikita Rjabovs, Vitalijs Stepanovs, Dmitrijs Turks, Maris |
author_facet | Semjonovs, Nikita Rjabovs, Vitalijs Stepanovs, Dmitrijs Turks, Maris |
author_sort | Semjonovs, Nikita |
collection | PubMed |
description | The title compound, C(23)H(25)N(3)O(4), {systematic name: 1-benzyl-4-[(3aR,5R,6R,6aR)-6-benzyloxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl]-1H-1,2,3-triazole}, consists of a substituted 2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxole. The furanose ring adopts an envelope conformation close to C (3)-exo, where the C atom substituted by the benzyloxy group is the flap. The fused dioxolane ring also adopts an envelope conformation, with the methylene C atom as the flap. In the crystal, molecules are linked by weak C—H⋯O hydrogen bonds, forming zigzag chains along [010]. |
format | Online Article Text |
id | pubmed-4719834 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-47198342016-02-11 Crystal structure of 3-O-benzyl-4(R)-C-(1-benzyl-1H-1,2,3-triazol-4-yl)-1,2-O-isopropylidene-α-d-erythrofuranose Semjonovs, Nikita Rjabovs, Vitalijs Stepanovs, Dmitrijs Turks, Maris Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(23)H(25)N(3)O(4), {systematic name: 1-benzyl-4-[(3aR,5R,6R,6aR)-6-benzyloxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl]-1H-1,2,3-triazole}, consists of a substituted 2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxole. The furanose ring adopts an envelope conformation close to C (3)-exo, where the C atom substituted by the benzyloxy group is the flap. The fused dioxolane ring also adopts an envelope conformation, with the methylene C atom as the flap. In the crystal, molecules are linked by weak C—H⋯O hydrogen bonds, forming zigzag chains along [010]. International Union of Crystallography 2015-11-28 /pmc/articles/PMC4719834/ /pubmed/26870425 http://dx.doi.org/10.1107/S2056989015022434 Text en © Semjonovs et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Semjonovs, Nikita Rjabovs, Vitalijs Stepanovs, Dmitrijs Turks, Maris Crystal structure of 3-O-benzyl-4(R)-C-(1-benzyl-1H-1,2,3-triazol-4-yl)-1,2-O-isopropylidene-α-d-erythrofuranose |
title | Crystal structure of 3-O-benzyl-4(R)-C-(1-benzyl-1H-1,2,3-triazol-4-yl)-1,2-O-isopropylidene-α-d-erythrofuranose |
title_full | Crystal structure of 3-O-benzyl-4(R)-C-(1-benzyl-1H-1,2,3-triazol-4-yl)-1,2-O-isopropylidene-α-d-erythrofuranose |
title_fullStr | Crystal structure of 3-O-benzyl-4(R)-C-(1-benzyl-1H-1,2,3-triazol-4-yl)-1,2-O-isopropylidene-α-d-erythrofuranose |
title_full_unstemmed | Crystal structure of 3-O-benzyl-4(R)-C-(1-benzyl-1H-1,2,3-triazol-4-yl)-1,2-O-isopropylidene-α-d-erythrofuranose |
title_short | Crystal structure of 3-O-benzyl-4(R)-C-(1-benzyl-1H-1,2,3-triazol-4-yl)-1,2-O-isopropylidene-α-d-erythrofuranose |
title_sort | crystal structure of 3-o-benzyl-4(r)-c-(1-benzyl-1h-1,2,3-triazol-4-yl)-1,2-o-isopropylidene-α-d-erythrofuranose |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719834/ https://www.ncbi.nlm.nih.gov/pubmed/26870425 http://dx.doi.org/10.1107/S2056989015022434 |
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