Crystal structure of bis­{μ-1-[(E)-(3-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ(3) N (2),O:O}bis­({1-[(E)-(3-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ(2) N (2),O}copper(II))

The title dinuclear Cu(II) complex, [Cu(2)(C(17)H(13)N(2)O(2))(4)], is located on an inversion centre. The Cu(II) atoms are each five-coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from two bidentate ligands and one bridging O atom from another ligand. In the din...

Descripción completa

Detalles Bibliográficos
Autores principales: Chetioui, Souheyla, Hamdouni, Noudjoud, Bochet, Christian G., Djukic, Jean-Pierre, Bailly, Corinne
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719838/
https://www.ncbi.nlm.nih.gov/pubmed/26870429
http://dx.doi.org/10.1107/S2056989015020824
_version_ 1782410984658305024
author Chetioui, Souheyla
Hamdouni, Noudjoud
Bochet, Christian G.
Djukic, Jean-Pierre
Bailly, Corinne
author_facet Chetioui, Souheyla
Hamdouni, Noudjoud
Bochet, Christian G.
Djukic, Jean-Pierre
Bailly, Corinne
author_sort Chetioui, Souheyla
collection PubMed
description The title dinuclear Cu(II) complex, [Cu(2)(C(17)H(13)N(2)O(2))(4)], is located on an inversion centre. The Cu(II) atoms are each five-coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from two bidentate ligands and one bridging O atom from another ligand. In the dinuclear complex, the Cu⋯Cu separation is 3.366 (3) Å. In the crystal, complex mol­ecules are linked via weak C—H⋯O hydrogen bonds, forming a layer parallel to (-101).
format Online
Article
Text
id pubmed-4719838
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-47198382016-02-11 Crystal structure of bis­{μ-1-[(E)-(3-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ(3) N (2),O:O}bis­({1-[(E)-(3-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ(2) N (2),O}copper(II)) Chetioui, Souheyla Hamdouni, Noudjoud Bochet, Christian G. Djukic, Jean-Pierre Bailly, Corinne Acta Crystallogr E Crystallogr Commun Data Reports The title dinuclear Cu(II) complex, [Cu(2)(C(17)H(13)N(2)O(2))(4)], is located on an inversion centre. The Cu(II) atoms are each five-coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from two bidentate ligands and one bridging O atom from another ligand. In the dinuclear complex, the Cu⋯Cu separation is 3.366 (3) Å. In the crystal, complex mol­ecules are linked via weak C—H⋯O hydrogen bonds, forming a layer parallel to (-101). International Union of Crystallography 2015-11-07 /pmc/articles/PMC4719838/ /pubmed/26870429 http://dx.doi.org/10.1107/S2056989015020824 Text en © Chetioui et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Chetioui, Souheyla
Hamdouni, Noudjoud
Bochet, Christian G.
Djukic, Jean-Pierre
Bailly, Corinne
Crystal structure of bis­{μ-1-[(E)-(3-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ(3) N (2),O:O}bis­({1-[(E)-(3-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ(2) N (2),O}copper(II))
title Crystal structure of bis­{μ-1-[(E)-(3-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ(3) N (2),O:O}bis­({1-[(E)-(3-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ(2) N (2),O}copper(II))
title_full Crystal structure of bis­{μ-1-[(E)-(3-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ(3) N (2),O:O}bis­({1-[(E)-(3-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ(2) N (2),O}copper(II))
title_fullStr Crystal structure of bis­{μ-1-[(E)-(3-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ(3) N (2),O:O}bis­({1-[(E)-(3-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ(2) N (2),O}copper(II))
title_full_unstemmed Crystal structure of bis­{μ-1-[(E)-(3-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ(3) N (2),O:O}bis­({1-[(E)-(3-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ(2) N (2),O}copper(II))
title_short Crystal structure of bis­{μ-1-[(E)-(3-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ(3) N (2),O:O}bis­({1-[(E)-(3-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ(2) N (2),O}copper(II))
title_sort crystal structure of bis­{μ-1-[(e)-(3-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ(3) n (2),o:o}bis­({1-[(e)-(3-meth­oxy­phen­yl)diazen­yl]naphthalen-2-olato-κ(2) n (2),o}copper(ii))
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719838/
https://www.ncbi.nlm.nih.gov/pubmed/26870429
http://dx.doi.org/10.1107/S2056989015020824
work_keys_str_mv AT chetiouisouheyla crystalstructureofbism1e3methoxyphenyldiazenylnaphthalen2olatok3n2oobis1e3methoxyphenyldiazenylnaphthalen2olatok2n2ocopperii
AT hamdouninoudjoud crystalstructureofbism1e3methoxyphenyldiazenylnaphthalen2olatok3n2oobis1e3methoxyphenyldiazenylnaphthalen2olatok2n2ocopperii
AT bochetchristiang crystalstructureofbism1e3methoxyphenyldiazenylnaphthalen2olatok3n2oobis1e3methoxyphenyldiazenylnaphthalen2olatok2n2ocopperii
AT djukicjeanpierre crystalstructureofbism1e3methoxyphenyldiazenylnaphthalen2olatok3n2oobis1e3methoxyphenyldiazenylnaphthalen2olatok2n2ocopperii
AT baillycorinne crystalstructureofbism1e3methoxyphenyldiazenylnaphthalen2olatok3n2oobis1e3methoxyphenyldiazenylnaphthalen2olatok2n2ocopperii

Ejemplares similares