Crystal structure of 1,1′-bis­(2-meth­oxy­carbonyl-2-methyl­prop­yl)ferrocene

The Fe atom in the title ferrocene derivative, [Fe(C(11)H(15)O(2))(2)], is situated on an inversion centre. As a result of the point-group symmetry -1 of the mol­ecule, the ferrocene moiety adopts a staggered conformation. The average Fe—C(Cp) bond length (Cp is cyclo­penta­dien­yl) is 2.045 (4) Å,...

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Detalles Bibliográficos
Autores principales: Guo, Yan-Feng, Wang, Jian-Jun, Xu, Wei-Juan, Sun, Dong-Hao, Gao, Qiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719839/
https://www.ncbi.nlm.nih.gov/pubmed/26870430
http://dx.doi.org/10.1107/S2056989015020642
Descripción
Sumario:The Fe atom in the title ferrocene derivative, [Fe(C(11)H(15)O(2))(2)], is situated on an inversion centre. As a result of the point-group symmetry -1 of the mol­ecule, the ferrocene moiety adopts a staggered conformation. The average Fe—C(Cp) bond length (Cp is cyclo­penta­dien­yl) is 2.045 (4) Å, in agreement with that of other disubstituted ferrocenes. The Fe—C bond length involving the substituted C atom is slightly longer [2.0521 (17) Å] than the remaining Fe—C bond lengths caused by the inductive effect of the methyl­ene group on the Cp ring. Apart from van der Waals forces, no significant inter­molecular inter­actions are observed in the crystal packing.

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