Crystal structure of 1,1′-bis­(2-meth­oxy­carbonyl-2-methyl­prop­yl)ferrocene

The Fe atom in the title ferrocene derivative, [Fe(C(11)H(15)O(2))(2)], is situated on an inversion centre. As a result of the point-group symmetry -1 of the mol­ecule, the ferrocene moiety adopts a staggered conformation. The average Fe—C(Cp) bond length (Cp is cyclo­penta­dien­yl) is 2.045 (4) Å,...

Descripción completa

Detalles Bibliográficos
Autores principales: Guo, Yan-Feng, Wang, Jian-Jun, Xu, Wei-Juan, Sun, Dong-Hao, Gao, Qiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719839/
https://www.ncbi.nlm.nih.gov/pubmed/26870430
http://dx.doi.org/10.1107/S2056989015020642
_version_ 1782410984879554560
author Guo, Yan-Feng
Wang, Jian-Jun
Xu, Wei-Juan
Sun, Dong-Hao
Gao, Qiang
author_facet Guo, Yan-Feng
Wang, Jian-Jun
Xu, Wei-Juan
Sun, Dong-Hao
Gao, Qiang
author_sort Guo, Yan-Feng
collection PubMed
description The Fe atom in the title ferrocene derivative, [Fe(C(11)H(15)O(2))(2)], is situated on an inversion centre. As a result of the point-group symmetry -1 of the mol­ecule, the ferrocene moiety adopts a staggered conformation. The average Fe—C(Cp) bond length (Cp is cyclo­penta­dien­yl) is 2.045 (4) Å, in agreement with that of other disubstituted ferrocenes. The Fe—C bond length involving the substituted C atom is slightly longer [2.0521 (17) Å] than the remaining Fe—C bond lengths caused by the inductive effect of the methyl­ene group on the Cp ring. Apart from van der Waals forces, no significant inter­molecular inter­actions are observed in the crystal packing.
format Online
Article
Text
id pubmed-4719839
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-47198392016-02-11 Crystal structure of 1,1′-bis­(2-meth­oxy­carbonyl-2-methyl­prop­yl)ferrocene Guo, Yan-Feng Wang, Jian-Jun Xu, Wei-Juan Sun, Dong-Hao Gao, Qiang Acta Crystallogr E Crystallogr Commun Data Reports The Fe atom in the title ferrocene derivative, [Fe(C(11)H(15)O(2))(2)], is situated on an inversion centre. As a result of the point-group symmetry -1 of the mol­ecule, the ferrocene moiety adopts a staggered conformation. The average Fe—C(Cp) bond length (Cp is cyclo­penta­dien­yl) is 2.045 (4) Å, in agreement with that of other disubstituted ferrocenes. The Fe—C bond length involving the substituted C atom is slightly longer [2.0521 (17) Å] than the remaining Fe—C bond lengths caused by the inductive effect of the methyl­ene group on the Cp ring. Apart from van der Waals forces, no significant inter­molecular inter­actions are observed in the crystal packing. International Union of Crystallography 2015-11-07 /pmc/articles/PMC4719839/ /pubmed/26870430 http://dx.doi.org/10.1107/S2056989015020642 Text en © Guo et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Guo, Yan-Feng
Wang, Jian-Jun
Xu, Wei-Juan
Sun, Dong-Hao
Gao, Qiang
Crystal structure of 1,1′-bis­(2-meth­oxy­carbonyl-2-methyl­prop­yl)ferrocene
title Crystal structure of 1,1′-bis­(2-meth­oxy­carbonyl-2-methyl­prop­yl)ferrocene
title_full Crystal structure of 1,1′-bis­(2-meth­oxy­carbonyl-2-methyl­prop­yl)ferrocene
title_fullStr Crystal structure of 1,1′-bis­(2-meth­oxy­carbonyl-2-methyl­prop­yl)ferrocene
title_full_unstemmed Crystal structure of 1,1′-bis­(2-meth­oxy­carbonyl-2-methyl­prop­yl)ferrocene
title_short Crystal structure of 1,1′-bis­(2-meth­oxy­carbonyl-2-methyl­prop­yl)ferrocene
title_sort crystal structure of 1,1′-bis­(2-meth­oxy­carbonyl-2-methyl­prop­yl)ferrocene
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719839/
https://www.ncbi.nlm.nih.gov/pubmed/26870430
http://dx.doi.org/10.1107/S2056989015020642
work_keys_str_mv AT guoyanfeng crystalstructureof11bis2methoxycarbonyl2methylpropylferrocene
AT wangjianjun crystalstructureof11bis2methoxycarbonyl2methylpropylferrocene
AT xuweijuan crystalstructureof11bis2methoxycarbonyl2methylpropylferrocene
AT sundonghao crystalstructureof11bis2methoxycarbonyl2methylpropylferrocene
AT gaoqiang crystalstructureof11bis2methoxycarbonyl2methylpropylferrocene

Ejemplares similares