Crystal structure of tris­(N-methyl­salicylaldiminato-κ(2) N,O)vanadium(III)

The structure of the title complex, [V(C(8)H(8)NO)(3)], comprises neutral and discrete complexes, in which the V(III) cation is coordinated by three anionic N-methyl­alicylaldiminate ligands within a slightly distorted mer-N(3)O(3) octa­hedral geometry. In the crystal structure, the mol­ecules are l...

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Detalles Bibliográficos
Autores principales: Hilbert, Jessica, Kabus, Sven, Näther, Christian, Bensch, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719845/
https://www.ncbi.nlm.nih.gov/pubmed/26870436
http://dx.doi.org/10.1107/S2056989015021453
Descripción
Sumario:The structure of the title complex, [V(C(8)H(8)NO)(3)], comprises neutral and discrete complexes, in which the V(III) cation is coordinated by three anionic N-methyl­alicylaldiminate ligands within a slightly distorted mer-N(3)O(3) octa­hedral geometry. In the crystal structure, the mol­ecules are linked via C—H⋯O hydrogen bonds into supra­molecular chains that extend along the c axis.

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