Crystal structure of tris­(N-methyl­salicylaldiminato-κ(2) N,O)vanadium(III)

The structure of the title complex, [V(C(8)H(8)NO)(3)], comprises neutral and discrete complexes, in which the V(III) cation is coordinated by three anionic N-methyl­alicylaldiminate ligands within a slightly distorted mer-N(3)O(3) octa­hedral geometry. In the crystal structure, the mol­ecules are l...

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Detalles Bibliográficos
Autores principales: Hilbert, Jessica, Kabus, Sven, Näther, Christian, Bensch, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719845/
https://www.ncbi.nlm.nih.gov/pubmed/26870436
http://dx.doi.org/10.1107/S2056989015021453
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author Hilbert, Jessica
Kabus, Sven
Näther, Christian
Bensch, Wolfgang
author_facet Hilbert, Jessica
Kabus, Sven
Näther, Christian
Bensch, Wolfgang
author_sort Hilbert, Jessica
collection PubMed
description The structure of the title complex, [V(C(8)H(8)NO)(3)], comprises neutral and discrete complexes, in which the V(III) cation is coordinated by three anionic N-methyl­alicylaldiminate ligands within a slightly distorted mer-N(3)O(3) octa­hedral geometry. In the crystal structure, the mol­ecules are linked via C—H⋯O hydrogen bonds into supra­molecular chains that extend along the c axis.
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spelling pubmed-47198452016-02-11 Crystal structure of tris­(N-methyl­salicylaldiminato-κ(2) N,O)vanadium(III) Hilbert, Jessica Kabus, Sven Näther, Christian Bensch, Wolfgang Acta Crystallogr E Crystallogr Commun Data Reports The structure of the title complex, [V(C(8)H(8)NO)(3)], comprises neutral and discrete complexes, in which the V(III) cation is coordinated by three anionic N-methyl­alicylaldiminate ligands within a slightly distorted mer-N(3)O(3) octa­hedral geometry. In the crystal structure, the mol­ecules are linked via C—H⋯O hydrogen bonds into supra­molecular chains that extend along the c axis. International Union of Crystallography 2015-11-18 /pmc/articles/PMC4719845/ /pubmed/26870436 http://dx.doi.org/10.1107/S2056989015021453 Text en © Hilbert et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Hilbert, Jessica
Kabus, Sven
Näther, Christian
Bensch, Wolfgang
Crystal structure of tris­(N-methyl­salicylaldiminato-κ(2) N,O)vanadium(III)
title Crystal structure of tris­(N-methyl­salicylaldiminato-κ(2) N,O)vanadium(III)
title_full Crystal structure of tris­(N-methyl­salicylaldiminato-κ(2) N,O)vanadium(III)
title_fullStr Crystal structure of tris­(N-methyl­salicylaldiminato-κ(2) N,O)vanadium(III)
title_full_unstemmed Crystal structure of tris­(N-methyl­salicylaldiminato-κ(2) N,O)vanadium(III)
title_short Crystal structure of tris­(N-methyl­salicylaldiminato-κ(2) N,O)vanadium(III)
title_sort crystal structure of tris­(n-methyl­salicylaldiminato-κ(2) n,o)vanadium(iii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719845/
https://www.ncbi.nlm.nih.gov/pubmed/26870436
http://dx.doi.org/10.1107/S2056989015021453
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