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Crystal structure of bis­(1,3-di­amino­propane-κ(2) N,N′)bis­[2-(4-nitro­phen­yl)acetato-κO]zinc(II)

In the structure of the title compound, [Zn(C(8)H(6)NO(4))(2)(C(3)H(10)N(2))(2)], the Zn(II) atom is located on a center of symmetry with one independent Zn—O distance of 2.199 (2) Å, and two Zn—N distances of 2.157 (2) and 2.144 (2) Å. The overall coordination geometry around the Zn(II) atom is oct...

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Autores principales: Roberts, T. J., Mehari, T. F., Assefa, Z., Hamby, T., Sykora, R. E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719853/
https://www.ncbi.nlm.nih.gov/pubmed/26870444
http://dx.doi.org/10.1107/S2056989015022380
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author Roberts, T. J.
Mehari, T. F.
Assefa, Z.
Hamby, T.
Sykora, R. E.
author_facet Roberts, T. J.
Mehari, T. F.
Assefa, Z.
Hamby, T.
Sykora, R. E.
author_sort Roberts, T. J.
collection PubMed
description In the structure of the title compound, [Zn(C(8)H(6)NO(4))(2)(C(3)H(10)N(2))(2)], the Zn(II) atom is located on a center of symmetry with one independent Zn—O distance of 2.199 (2) Å, and two Zn—N distances of 2.157 (2) and 2.144 (2) Å. The overall coordination geometry around the Zn(II) atom is octa­hedral. Several types of hydrogen-bonding inter­actions are evident. Both intra­molecular [2.959 (3) Å] and inter­molecular [3.118 (3) and 3.124 (3) Å inter­actions occur between the O atoms of the acetate group and the amino N atoms, and weak inter­molecular C—H—O inter­actions involving the nitro groups, leading to an extended chain of the molecules aligned along the ac plane.
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spelling pubmed-47198532016-02-11 Crystal structure of bis­(1,3-di­amino­propane-κ(2) N,N′)bis­[2-(4-nitro­phen­yl)acetato-κO]zinc(II) Roberts, T. J. Mehari, T. F. Assefa, Z. Hamby, T. Sykora, R. E. Acta Crystallogr E Crystallogr Commun Data Reports In the structure of the title compound, [Zn(C(8)H(6)NO(4))(2)(C(3)H(10)N(2))(2)], the Zn(II) atom is located on a center of symmetry with one independent Zn—O distance of 2.199 (2) Å, and two Zn—N distances of 2.157 (2) and 2.144 (2) Å. The overall coordination geometry around the Zn(II) atom is octa­hedral. Several types of hydrogen-bonding inter­actions are evident. Both intra­molecular [2.959 (3) Å] and inter­molecular [3.118 (3) and 3.124 (3) Å inter­actions occur between the O atoms of the acetate group and the amino N atoms, and weak inter­molecular C—H—O inter­actions involving the nitro groups, leading to an extended chain of the molecules aligned along the ac plane. International Union of Crystallography 2015-12-06 /pmc/articles/PMC4719853/ /pubmed/26870444 http://dx.doi.org/10.1107/S2056989015022380 Text en © Roberts et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Roberts, T. J.
Mehari, T. F.
Assefa, Z.
Hamby, T.
Sykora, R. E.
Crystal structure of bis­(1,3-di­amino­propane-κ(2) N,N′)bis­[2-(4-nitro­phen­yl)acetato-κO]zinc(II)
title Crystal structure of bis­(1,3-di­amino­propane-κ(2) N,N′)bis­[2-(4-nitro­phen­yl)acetato-κO]zinc(II)
title_full Crystal structure of bis­(1,3-di­amino­propane-κ(2) N,N′)bis­[2-(4-nitro­phen­yl)acetato-κO]zinc(II)
title_fullStr Crystal structure of bis­(1,3-di­amino­propane-κ(2) N,N′)bis­[2-(4-nitro­phen­yl)acetato-κO]zinc(II)
title_full_unstemmed Crystal structure of bis­(1,3-di­amino­propane-κ(2) N,N′)bis­[2-(4-nitro­phen­yl)acetato-κO]zinc(II)
title_short Crystal structure of bis­(1,3-di­amino­propane-κ(2) N,N′)bis­[2-(4-nitro­phen­yl)acetato-κO]zinc(II)
title_sort crystal structure of bis­(1,3-di­amino­propane-κ(2) n,n′)bis­[2-(4-nitro­phen­yl)acetato-κo]zinc(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719853/
https://www.ncbi.nlm.nih.gov/pubmed/26870444
http://dx.doi.org/10.1107/S2056989015022380
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