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Crystal structure of bis(1,3-diaminopropane-κ(2) N,N′)bis[2-(4-nitrophenyl)acetato-κO]zinc(II)
In the structure of the title compound, [Zn(C(8)H(6)NO(4))(2)(C(3)H(10)N(2))(2)], the Zn(II) atom is located on a center of symmetry with one independent Zn—O distance of 2.199 (2) Å, and two Zn—N distances of 2.157 (2) and 2.144 (2) Å. The overall coordination geometry around the Zn(II) atom is oct...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719853/ https://www.ncbi.nlm.nih.gov/pubmed/26870444 http://dx.doi.org/10.1107/S2056989015022380 |
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author | Roberts, T. J. Mehari, T. F. Assefa, Z. Hamby, T. Sykora, R. E. |
author_facet | Roberts, T. J. Mehari, T. F. Assefa, Z. Hamby, T. Sykora, R. E. |
author_sort | Roberts, T. J. |
collection | PubMed |
description | In the structure of the title compound, [Zn(C(8)H(6)NO(4))(2)(C(3)H(10)N(2))(2)], the Zn(II) atom is located on a center of symmetry with one independent Zn—O distance of 2.199 (2) Å, and two Zn—N distances of 2.157 (2) and 2.144 (2) Å. The overall coordination geometry around the Zn(II) atom is octahedral. Several types of hydrogen-bonding interactions are evident. Both intramolecular [2.959 (3) Å] and intermolecular [3.118 (3) and 3.124 (3) Å interactions occur between the O atoms of the acetate group and the amino N atoms, and weak intermolecular C—H—O interactions involving the nitro groups, leading to an extended chain of the molecules aligned along the ac plane. |
format | Online Article Text |
id | pubmed-4719853 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-47198532016-02-11 Crystal structure of bis(1,3-diaminopropane-κ(2) N,N′)bis[2-(4-nitrophenyl)acetato-κO]zinc(II) Roberts, T. J. Mehari, T. F. Assefa, Z. Hamby, T. Sykora, R. E. Acta Crystallogr E Crystallogr Commun Data Reports In the structure of the title compound, [Zn(C(8)H(6)NO(4))(2)(C(3)H(10)N(2))(2)], the Zn(II) atom is located on a center of symmetry with one independent Zn—O distance of 2.199 (2) Å, and two Zn—N distances of 2.157 (2) and 2.144 (2) Å. The overall coordination geometry around the Zn(II) atom is octahedral. Several types of hydrogen-bonding interactions are evident. Both intramolecular [2.959 (3) Å] and intermolecular [3.118 (3) and 3.124 (3) Å interactions occur between the O atoms of the acetate group and the amino N atoms, and weak intermolecular C—H—O interactions involving the nitro groups, leading to an extended chain of the molecules aligned along the ac plane. International Union of Crystallography 2015-12-06 /pmc/articles/PMC4719853/ /pubmed/26870444 http://dx.doi.org/10.1107/S2056989015022380 Text en © Roberts et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Roberts, T. J. Mehari, T. F. Assefa, Z. Hamby, T. Sykora, R. E. Crystal structure of bis(1,3-diaminopropane-κ(2) N,N′)bis[2-(4-nitrophenyl)acetato-κO]zinc(II) |
title | Crystal structure of bis(1,3-diaminopropane-κ(2)
N,N′)bis[2-(4-nitrophenyl)acetato-κO]zinc(II) |
title_full | Crystal structure of bis(1,3-diaminopropane-κ(2)
N,N′)bis[2-(4-nitrophenyl)acetato-κO]zinc(II) |
title_fullStr | Crystal structure of bis(1,3-diaminopropane-κ(2)
N,N′)bis[2-(4-nitrophenyl)acetato-κO]zinc(II) |
title_full_unstemmed | Crystal structure of bis(1,3-diaminopropane-κ(2)
N,N′)bis[2-(4-nitrophenyl)acetato-κO]zinc(II) |
title_short | Crystal structure of bis(1,3-diaminopropane-κ(2)
N,N′)bis[2-(4-nitrophenyl)acetato-κO]zinc(II) |
title_sort | crystal structure of bis(1,3-diaminopropane-κ(2)
n,n′)bis[2-(4-nitrophenyl)acetato-κo]zinc(ii) |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719853/ https://www.ncbi.nlm.nih.gov/pubmed/26870444 http://dx.doi.org/10.1107/S2056989015022380 |
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