Crystal structure of bis­{N-[(di­ethyl­amino)­dimethyl­sil­yl]anilido-κ(2) N,N′}zinc

The title zinc amide, [Zn(C(12)H(21)N(2)Si)(2)], was prepared by the metathetical reaction of [LiN(SiMe(2)NEt(2))(C(6)H(5))](2) with zinc dichloride. It is mononuclear and the mol­ecule is generated by twofold rotation symmetry. The central Zn(II) atom is N,N′-chelated by each of the two N-silylated...

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Autor principal: Chen, Juan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719856/
https://www.ncbi.nlm.nih.gov/pubmed/26870447
http://dx.doi.org/10.1107/S2056989015022768
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author Chen, Juan
author_facet Chen, Juan
author_sort Chen, Juan
collection PubMed
description The title zinc amide, [Zn(C(12)H(21)N(2)Si)(2)], was prepared by the metathetical reaction of [LiN(SiMe(2)NEt(2))(C(6)H(5))](2) with zinc dichloride. It is mononuclear and the mol­ecule is generated by twofold rotation symmetry. The central Zn(II) atom is N,N′-chelated by each of the two N-silylated anilide ligands in a highly distorted tetra­hedral environment. Two N—Si—N ligands are arranged in a cis fashion around the Zn(II) atom. The Zn—N(amine) bonds [2.2315 (12) Å] are much longer than the Zn—N(anilide) bonds [1.9367 (11) Å].
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spelling pubmed-47198562016-02-11 Crystal structure of bis­{N-[(di­ethyl­amino)­dimethyl­sil­yl]anilido-κ(2) N,N′}zinc Chen, Juan Acta Crystallogr E Crystallogr Commun Data Reports The title zinc amide, [Zn(C(12)H(21)N(2)Si)(2)], was prepared by the metathetical reaction of [LiN(SiMe(2)NEt(2))(C(6)H(5))](2) with zinc dichloride. It is mononuclear and the mol­ecule is generated by twofold rotation symmetry. The central Zn(II) atom is N,N′-chelated by each of the two N-silylated anilide ligands in a highly distorted tetra­hedral environment. Two N—Si—N ligands are arranged in a cis fashion around the Zn(II) atom. The Zn—N(amine) bonds [2.2315 (12) Å] are much longer than the Zn—N(anilide) bonds [1.9367 (11) Å]. International Union of Crystallography 2015-12-06 /pmc/articles/PMC4719856/ /pubmed/26870447 http://dx.doi.org/10.1107/S2056989015022768 Text en © Juan Chen 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Chen, Juan
Crystal structure of bis­{N-[(di­ethyl­amino)­dimethyl­sil­yl]anilido-κ(2) N,N′}zinc
title Crystal structure of bis­{N-[(di­ethyl­amino)­dimethyl­sil­yl]anilido-κ(2) N,N′}zinc
title_full Crystal structure of bis­{N-[(di­ethyl­amino)­dimethyl­sil­yl]anilido-κ(2) N,N′}zinc
title_fullStr Crystal structure of bis­{N-[(di­ethyl­amino)­dimethyl­sil­yl]anilido-κ(2) N,N′}zinc
title_full_unstemmed Crystal structure of bis­{N-[(di­ethyl­amino)­dimethyl­sil­yl]anilido-κ(2) N,N′}zinc
title_short Crystal structure of bis­{N-[(di­ethyl­amino)­dimethyl­sil­yl]anilido-κ(2) N,N′}zinc
title_sort crystal structure of bis­{n-[(di­ethyl­amino)­dimethyl­sil­yl]anilido-κ(2) n,n′}zinc
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719856/
https://www.ncbi.nlm.nih.gov/pubmed/26870447
http://dx.doi.org/10.1107/S2056989015022768
work_keys_str_mv AT chenjuan crystalstructureofbisndiethylaminodimethylsilylanilidok2nnzinc

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