Crystal structure of tris­(N-methyl­salicyl­aldiminato-κ(2) N,O)chromium(III)

The crystal structure of the title compound, [Cr(C(8)H(8)NO)(3)], is isotypic with the vanadium(III) analogue. The asymmetric unit consists of one Cr(3+) cation and three N-methyl­salicylaldiminate anions. The metal cation is octa­hedrally coordinated by three N,O-chelating N-methyl­salicylaldiminat...

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Autores principales: Hilbert, Jessica, Kabus, Sven, Näther, Christian, Bensch, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719857/
https://www.ncbi.nlm.nih.gov/pubmed/26870448
http://dx.doi.org/10.1107/S2056989015023038
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author Hilbert, Jessica
Kabus, Sven
Näther, Christian
Bensch, Wolfgang
author_facet Hilbert, Jessica
Kabus, Sven
Näther, Christian
Bensch, Wolfgang
author_sort Hilbert, Jessica
collection PubMed
description The crystal structure of the title compound, [Cr(C(8)H(8)NO)(3)], is isotypic with the vanadium(III) analogue. The asymmetric unit consists of one Cr(3+) cation and three N-methyl­salicylaldiminate anions. The metal cation is octa­hedrally coordinated by three N,O-chelating N-methyl­salicylaldiminate ligands, leading to discrete and neutral complexes. In the crystal, neighbouring complexes are linked via C—H⋯O hydrogen-bonding inter­actions into chains propagating parallel to the c axis.
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spelling pubmed-47198572016-02-11 Crystal structure of tris­(N-methyl­salicyl­aldiminato-κ(2) N,O)chromium(III) Hilbert, Jessica Kabus, Sven Näther, Christian Bensch, Wolfgang Acta Crystallogr E Crystallogr Commun Data Reports The crystal structure of the title compound, [Cr(C(8)H(8)NO)(3)], is isotypic with the vanadium(III) analogue. The asymmetric unit consists of one Cr(3+) cation and three N-methyl­salicylaldiminate anions. The metal cation is octa­hedrally coordinated by three N,O-chelating N-methyl­salicylaldiminate ligands, leading to discrete and neutral complexes. In the crystal, neighbouring complexes are linked via C—H⋯O hydrogen-bonding inter­actions into chains propagating parallel to the c axis. International Union of Crystallography 2015-12-06 /pmc/articles/PMC4719857/ /pubmed/26870448 http://dx.doi.org/10.1107/S2056989015023038 Text en © Hilbert et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Hilbert, Jessica
Kabus, Sven
Näther, Christian
Bensch, Wolfgang
Crystal structure of tris­(N-methyl­salicyl­aldiminato-κ(2) N,O)chromium(III)
title Crystal structure of tris­(N-methyl­salicyl­aldiminato-κ(2) N,O)chromium(III)
title_full Crystal structure of tris­(N-methyl­salicyl­aldiminato-κ(2) N,O)chromium(III)
title_fullStr Crystal structure of tris­(N-methyl­salicyl­aldiminato-κ(2) N,O)chromium(III)
title_full_unstemmed Crystal structure of tris­(N-methyl­salicyl­aldiminato-κ(2) N,O)chromium(III)
title_short Crystal structure of tris­(N-methyl­salicyl­aldiminato-κ(2) N,O)chromium(III)
title_sort crystal structure of tris­(n-methyl­salicyl­aldiminato-κ(2) n,o)chromium(iii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719857/
https://www.ncbi.nlm.nih.gov/pubmed/26870448
http://dx.doi.org/10.1107/S2056989015023038
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