Crystal structure of bis­(1,3-di­meth­oxy­imidazolin-2-yl­idene)silver(I) hexa­fluorido­phosphate, N-heterocyclic carbene (NHC) complex

The title salt, [Ag(C(5)H(8)N(2)O(2))(2)]PF(6), was obtained by deprotonation and metalation of 1,3-di­meth­oxy­imidazolium hexa­fluorido­phosphate using silver(I) oxide in methanol. The C—Ag—C angle in the cation is 178.1 (2)°, and the N—C—N angles are 101.1 (4) and 100.5 (4)°. The meth­oxy groups...

Descripción completa

Detalles Bibliográficos
Autores principales: Rietzler, Barbara, Laus, Gerhard, Kahlenberg, Volker, Schottenberger, Herwig
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719859/
https://www.ncbi.nlm.nih.gov/pubmed/26870450
http://dx.doi.org/10.1107/S2056989015023130
Descripción
Sumario:The title salt, [Ag(C(5)H(8)N(2)O(2))(2)]PF(6), was obtained by deprotonation and metalation of 1,3-di­meth­oxy­imidazolium hexa­fluorido­phosphate using silver(I) oxide in methanol. The C—Ag—C angle in the cation is 178.1 (2)°, and the N—C—N angles are 101.1 (4) and 100.5 (4)°. The meth­oxy groups adopt an anti conformation. In the crystal, anions (A) are sandwiched between cations (C) in a layered arrangement {C…A…C}(n) stacked along [001]. Within a C…A…C layer, the hexafluoridophosphate anions accept several C—H⋯F hydrogen bonds from the cationic complex.

Ejemplares similares