Crystal structure of bis­(1,3-di­meth­oxy­imidazolin-2-yl­idene)silver(I) hexa­fluorido­phosphate, N-heterocyclic carbene (NHC) complex

The title salt, [Ag(C(5)H(8)N(2)O(2))(2)]PF(6), was obtained by deprotonation and metalation of 1,3-di­meth­oxy­imidazolium hexa­fluorido­phosphate using silver(I) oxide in methanol. The C—Ag—C angle in the cation is 178.1 (2)°, and the N—C—N angles are 101.1 (4) and 100.5 (4)°. The meth­oxy groups...

Descripción completa

Detalles Bibliográficos
Autores principales: Rietzler, Barbara, Laus, Gerhard, Kahlenberg, Volker, Schottenberger, Herwig
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719859/
https://www.ncbi.nlm.nih.gov/pubmed/26870450
http://dx.doi.org/10.1107/S2056989015023130
_version_ 1782410989433520128
author Rietzler, Barbara
Laus, Gerhard
Kahlenberg, Volker
Schottenberger, Herwig
author_facet Rietzler, Barbara
Laus, Gerhard
Kahlenberg, Volker
Schottenberger, Herwig
author_sort Rietzler, Barbara
collection PubMed
description The title salt, [Ag(C(5)H(8)N(2)O(2))(2)]PF(6), was obtained by deprotonation and metalation of 1,3-di­meth­oxy­imidazolium hexa­fluorido­phosphate using silver(I) oxide in methanol. The C—Ag—C angle in the cation is 178.1 (2)°, and the N—C—N angles are 101.1 (4) and 100.5 (4)°. The meth­oxy groups adopt an anti conformation. In the crystal, anions (A) are sandwiched between cations (C) in a layered arrangement {C…A…C}(n) stacked along [001]. Within a C…A…C layer, the hexafluoridophosphate anions accept several C—H⋯F hydrogen bonds from the cationic complex.
format Online
Article
Text
id pubmed-4719859
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-47198592016-02-11 Crystal structure of bis­(1,3-di­meth­oxy­imidazolin-2-yl­idene)silver(I) hexa­fluorido­phosphate, N-heterocyclic carbene (NHC) complex Rietzler, Barbara Laus, Gerhard Kahlenberg, Volker Schottenberger, Herwig Acta Crystallogr E Crystallogr Commun Data Reports The title salt, [Ag(C(5)H(8)N(2)O(2))(2)]PF(6), was obtained by deprotonation and metalation of 1,3-di­meth­oxy­imidazolium hexa­fluorido­phosphate using silver(I) oxide in methanol. The C—Ag—C angle in the cation is 178.1 (2)°, and the N—C—N angles are 101.1 (4) and 100.5 (4)°. The meth­oxy groups adopt an anti conformation. In the crystal, anions (A) are sandwiched between cations (C) in a layered arrangement {C…A…C}(n) stacked along [001]. Within a C…A…C layer, the hexafluoridophosphate anions accept several C—H⋯F hydrogen bonds from the cationic complex. International Union of Crystallography 2015-12-09 /pmc/articles/PMC4719859/ /pubmed/26870450 http://dx.doi.org/10.1107/S2056989015023130 Text en © Rietzler et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Rietzler, Barbara
Laus, Gerhard
Kahlenberg, Volker
Schottenberger, Herwig
Crystal structure of bis­(1,3-di­meth­oxy­imidazolin-2-yl­idene)silver(I) hexa­fluorido­phosphate, N-heterocyclic carbene (NHC) complex
title Crystal structure of bis­(1,3-di­meth­oxy­imidazolin-2-yl­idene)silver(I) hexa­fluorido­phosphate, N-heterocyclic carbene (NHC) complex
title_full Crystal structure of bis­(1,3-di­meth­oxy­imidazolin-2-yl­idene)silver(I) hexa­fluorido­phosphate, N-heterocyclic carbene (NHC) complex
title_fullStr Crystal structure of bis­(1,3-di­meth­oxy­imidazolin-2-yl­idene)silver(I) hexa­fluorido­phosphate, N-heterocyclic carbene (NHC) complex
title_full_unstemmed Crystal structure of bis­(1,3-di­meth­oxy­imidazolin-2-yl­idene)silver(I) hexa­fluorido­phosphate, N-heterocyclic carbene (NHC) complex
title_short Crystal structure of bis­(1,3-di­meth­oxy­imidazolin-2-yl­idene)silver(I) hexa­fluorido­phosphate, N-heterocyclic carbene (NHC) complex
title_sort crystal structure of bis­(1,3-di­meth­oxy­imidazolin-2-yl­idene)silver(i) hexa­fluorido­phosphate, n-heterocyclic carbene (nhc) complex
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719859/
https://www.ncbi.nlm.nih.gov/pubmed/26870450
http://dx.doi.org/10.1107/S2056989015023130
work_keys_str_mv AT rietzlerbarbara crystalstructureofbis13dimethoxyimidazolin2ylidenesilverihexafluoridophosphatenheterocycliccarbenenhccomplex
AT lausgerhard crystalstructureofbis13dimethoxyimidazolin2ylidenesilverihexafluoridophosphatenheterocycliccarbenenhccomplex
AT kahlenbergvolker crystalstructureofbis13dimethoxyimidazolin2ylidenesilverihexafluoridophosphatenheterocycliccarbenenhccomplex
AT schottenbergerherwig crystalstructureofbis13dimethoxyimidazolin2ylidenesilverihexafluoridophosphatenheterocycliccarbenenhccomplex

Ejemplares similares