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Crystal structure of di-μ(2)-chlorido-bis[(1-aza-4-azoniabicyclo[2.2.2]octane-κN (1))dichloridodicadmium]
In the structure of the binuclear title compound, [Cd(2)(C(6)H(13)N(2))(2)Cl(6)], two Cd(II) atoms are bridged by two Cl(−) ligands, defining a centrosymmetric Cd(2)Cl(2) motif. Each metal cation is additionally coordinated by two Cl(−) ligands and the N atom of a protonated 1,4-diazabicyclo[2.2....
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719863/ https://www.ncbi.nlm.nih.gov/pubmed/26870454 http://dx.doi.org/10.1107/S2056989015023361 |
Sumario: | In the structure of the binuclear title compound, [Cd(2)(C(6)H(13)N(2))(2)Cl(6)], two Cd(II) atoms are bridged by two Cl(−) ligands, defining a centrosymmetric Cd(2)Cl(2) motif. Each metal cation is additionally coordinated by two Cl(−) ligands and the N atom of a protonated 1,4-diazabicyclo[2.2.2]octane (H-DABCO)(+) ligand, leading to an overall trigonal–bipyramidal coordination environment with one of the bridging Cl(−) ligands and the N atom at the apical sites. In the crystal, the neutral dimers are linked via N—H⋯Cl hydrogen bonds, forming a two-dimensional network expanding parallel to (100). |
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