Crystal structure of di­bromido­tetra­kis(propan-2-ol-κO)nickel(II)

The asymmetric unit of the mononuclear title complex, [NiBr(2)(C(3)H(8)O)(4)], comprises a Ni(II) cation located on a centre of inversion, one Br(−) anion and two propan-2-ol ligands. The Ni(II) cation exhibits a distorted trans-Br(2)O(4) environment. There are O—H⋯Br hydrogen bonds connecting neigh...

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Detalles Bibliográficos
Autores principales: Lv, Yaokang, Liu, Mingxian, Ji, Lvlv, Zhang, Cheng, Ouyang, Mi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719865/
https://www.ncbi.nlm.nih.gov/pubmed/26870456
http://dx.doi.org/10.1107/S2056989015023555
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author Lv, Yaokang
Liu, Mingxian
Ji, Lvlv
Zhang, Cheng
Ouyang, Mi
author_facet Lv, Yaokang
Liu, Mingxian
Ji, Lvlv
Zhang, Cheng
Ouyang, Mi
author_sort Lv, Yaokang
collection PubMed
description The asymmetric unit of the mononuclear title complex, [NiBr(2)(C(3)H(8)O)(4)], comprises a Ni(II) cation located on a centre of inversion, one Br(−) anion and two propan-2-ol ligands. The Ni(II) cation exhibits a distorted trans-Br(2)O(4) environment. There are O—H⋯Br hydrogen bonds connecting neighbouring mol­ecules into rows along [100]. These rows are arranged in a distorted hexa­gonal packing and are held together by van der Waals forces only.
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spelling pubmed-47198652016-02-11 Crystal structure of di­bromido­tetra­kis(propan-2-ol-κO)nickel(II) Lv, Yaokang Liu, Mingxian Ji, Lvlv Zhang, Cheng Ouyang, Mi Acta Crystallogr E Crystallogr Commun Data Reports The asymmetric unit of the mononuclear title complex, [NiBr(2)(C(3)H(8)O)(4)], comprises a Ni(II) cation located on a centre of inversion, one Br(−) anion and two propan-2-ol ligands. The Ni(II) cation exhibits a distorted trans-Br(2)O(4) environment. There are O—H⋯Br hydrogen bonds connecting neighbouring mol­ecules into rows along [100]. These rows are arranged in a distorted hexa­gonal packing and are held together by van der Waals forces only. International Union of Crystallography 2015-12-19 /pmc/articles/PMC4719865/ /pubmed/26870456 http://dx.doi.org/10.1107/S2056989015023555 Text en © Lv et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Lv, Yaokang
Liu, Mingxian
Ji, Lvlv
Zhang, Cheng
Ouyang, Mi
Crystal structure of di­bromido­tetra­kis(propan-2-ol-κO)nickel(II)
title Crystal structure of di­bromido­tetra­kis(propan-2-ol-κO)nickel(II)
title_full Crystal structure of di­bromido­tetra­kis(propan-2-ol-κO)nickel(II)
title_fullStr Crystal structure of di­bromido­tetra­kis(propan-2-ol-κO)nickel(II)
title_full_unstemmed Crystal structure of di­bromido­tetra­kis(propan-2-ol-κO)nickel(II)
title_short Crystal structure of di­bromido­tetra­kis(propan-2-ol-κO)nickel(II)
title_sort crystal structure of di­bromido­tetra­kis(propan-2-ol-κo)nickel(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719865/
https://www.ncbi.nlm.nih.gov/pubmed/26870456
http://dx.doi.org/10.1107/S2056989015023555
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