Crystal structure of bis­(μ-2-benzoyl­benzoato-κ(2) O:O′)bis­[bis­(2,2′-bi­pyridine-κ(2) N,N′)manganese(II)] bis­(perchlorate)

The title compound, [Mn(2)(C(6)H(5)COC(6)H(4)COO)(2)(C(10)H(8)N(2))(4)](ClO(4))(2), comprises a centrosymmetric binuclear cation and two perchlorate anions. In the complex cation, two Mn(II) atoms are bridged by two O atoms of two different 2-benzoyl­benzoate ligands, each Mn(II) atom being further...

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Detalles Bibliográficos
Autor principal: Kani, Ibrahim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719866/
https://www.ncbi.nlm.nih.gov/pubmed/26870457
http://dx.doi.org/10.1107/S2056989015023671
Descripción
Sumario:The title compound, [Mn(2)(C(6)H(5)COC(6)H(4)COO)(2)(C(10)H(8)N(2))(4)](ClO(4))(2), comprises a centrosymmetric binuclear cation and two perchlorate anions. In the complex cation, two Mn(II) atoms are bridged by two O atoms of two different 2-benzoyl­benzoate ligands, each Mn(II) atom being further coordinated by two 2,2′-bi­pyridine (bipy) ligands in a distorted octa­hedral environment. Within the binuclear mol­ecule, the Mn⋯Mn separation is 4.513 (7) Å. Inter­molecular C—H⋯O and C—H⋯ π inter­actions link the mol­ecules into a three-dimensional network.

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