Crystal structure of bis­(μ-2-benzoyl­benzoato-κ(2) O:O′)bis­[bis­(2,2′-bi­pyridine-κ(2) N,N′)manganese(II)] bis­(perchlorate)

The title compound, [Mn(2)(C(6)H(5)COC(6)H(4)COO)(2)(C(10)H(8)N(2))(4)](ClO(4))(2), comprises a centrosymmetric binuclear cation and two perchlorate anions. In the complex cation, two Mn(II) atoms are bridged by two O atoms of two different 2-benzoyl­benzoate ligands, each Mn(II) atom being further...

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Detalles Bibliográficos
Autor principal: Kani, Ibrahim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719866/
https://www.ncbi.nlm.nih.gov/pubmed/26870457
http://dx.doi.org/10.1107/S2056989015023671
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author Kani, Ibrahim
author_facet Kani, Ibrahim
author_sort Kani, Ibrahim
collection PubMed
description The title compound, [Mn(2)(C(6)H(5)COC(6)H(4)COO)(2)(C(10)H(8)N(2))(4)](ClO(4))(2), comprises a centrosymmetric binuclear cation and two perchlorate anions. In the complex cation, two Mn(II) atoms are bridged by two O atoms of two different 2-benzoyl­benzoate ligands, each Mn(II) atom being further coordinated by two 2,2′-bi­pyridine (bipy) ligands in a distorted octa­hedral environment. Within the binuclear mol­ecule, the Mn⋯Mn separation is 4.513 (7) Å. Inter­molecular C—H⋯O and C—H⋯ π inter­actions link the mol­ecules into a three-dimensional network.
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spelling pubmed-47198662016-02-11 Crystal structure of bis­(μ-2-benzoyl­benzoato-κ(2) O:O′)bis­[bis­(2,2′-bi­pyridine-κ(2) N,N′)manganese(II)] bis­(perchlorate) Kani, Ibrahim Acta Crystallogr E Crystallogr Commun Data Reports The title compound, [Mn(2)(C(6)H(5)COC(6)H(4)COO)(2)(C(10)H(8)N(2))(4)](ClO(4))(2), comprises a centrosymmetric binuclear cation and two perchlorate anions. In the complex cation, two Mn(II) atoms are bridged by two O atoms of two different 2-benzoyl­benzoate ligands, each Mn(II) atom being further coordinated by two 2,2′-bi­pyridine (bipy) ligands in a distorted octa­hedral environment. Within the binuclear mol­ecule, the Mn⋯Mn separation is 4.513 (7) Å. Inter­molecular C—H⋯O and C—H⋯ π inter­actions link the mol­ecules into a three-dimensional network. International Union of Crystallography 2015-12-16 /pmc/articles/PMC4719866/ /pubmed/26870457 http://dx.doi.org/10.1107/S2056989015023671 Text en © Ibrahim Kani 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Kani, Ibrahim
Crystal structure of bis­(μ-2-benzoyl­benzoato-κ(2) O:O′)bis­[bis­(2,2′-bi­pyridine-κ(2) N,N′)manganese(II)] bis­(perchlorate)
title Crystal structure of bis­(μ-2-benzoyl­benzoato-κ(2) O:O′)bis­[bis­(2,2′-bi­pyridine-κ(2) N,N′)manganese(II)] bis­(perchlorate)
title_full Crystal structure of bis­(μ-2-benzoyl­benzoato-κ(2) O:O′)bis­[bis­(2,2′-bi­pyridine-κ(2) N,N′)manganese(II)] bis­(perchlorate)
title_fullStr Crystal structure of bis­(μ-2-benzoyl­benzoato-κ(2) O:O′)bis­[bis­(2,2′-bi­pyridine-κ(2) N,N′)manganese(II)] bis­(perchlorate)
title_full_unstemmed Crystal structure of bis­(μ-2-benzoyl­benzoato-κ(2) O:O′)bis­[bis­(2,2′-bi­pyridine-κ(2) N,N′)manganese(II)] bis­(perchlorate)
title_short Crystal structure of bis­(μ-2-benzoyl­benzoato-κ(2) O:O′)bis­[bis­(2,2′-bi­pyridine-κ(2) N,N′)manganese(II)] bis­(perchlorate)
title_sort crystal structure of bis­(μ-2-benzoyl­benzoato-κ(2) o:o′)bis­[bis­(2,2′-bi­pyridine-κ(2) n,n′)manganese(ii)] bis­(perchlorate)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719866/
https://www.ncbi.nlm.nih.gov/pubmed/26870457
http://dx.doi.org/10.1107/S2056989015023671
work_keys_str_mv AT kaniibrahim crystalstructureofbism2benzoylbenzoatok2oobisbis22bipyridinek2nnmanganeseiibisperchlorate

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