Crystal structure of tris­(μ-bis­{4-[(pyridin-2-yl­methyl­idene)amino]­phen­yl}methane-κ(4) N,N′:N′′,N′′′)dizinc tetra­kis­(tetra­fluorido­borate) aceto­nitrile tris­olvate

The asymmetric unit of the title compound, [Zn(2)(C(25)H(20)N(4))(3)](BF(4))(4)·3CH(3)CN, consists of one dinuclear Zn(II) complex cation with a triple-helical [Zn(2) L (3)](4+) motif (L is bis­{4-[(pyridin-2-yl­methyl­idene)amino]­phen­yl}methane), four BF(4) (−) anions and three CH(3)CN solvent mo...

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Autores principales: Alexandru, Maria-Gabriela, Dumitru, Florina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719869/
https://www.ncbi.nlm.nih.gov/pubmed/26870460
http://dx.doi.org/10.1107/S205698901502455X
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author Alexandru, Maria-Gabriela
Dumitru, Florina
author_facet Alexandru, Maria-Gabriela
Dumitru, Florina
author_sort Alexandru, Maria-Gabriela
collection PubMed
description The asymmetric unit of the title compound, [Zn(2)(C(25)H(20)N(4))(3)](BF(4))(4)·3CH(3)CN, consists of one dinuclear Zn(II) complex cation with a triple-helical [Zn(2) L (3)](4+) motif (L is bis­{4-[(pyridin-2-yl­methyl­idene)amino]­phen­yl}methane), four BF(4) (−) anions and three CH(3)CN solvent mol­ecules. The Zn⋯Zn separation is 11.3893 (14) Å and the ligands wrap around the two Zn(II) atoms, forming a triple helix as defined by the Zn—N—N—Zn torsion angles of 104.05 (18), 99.06 (19) and 101.40 (19)°. The Zn—N(pyrid­yl) distances in the octahedral ZnN(6) coordination sphere are in the range 2.128 (5)–2.190 (5) Å and the Zn—N(imine) distances are in the range 2.157 (5)–2.277 (5) Å.
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spelling pubmed-47198692016-02-11 Crystal structure of tris­(μ-bis­{4-[(pyridin-2-yl­methyl­idene)amino]­phen­yl}methane-κ(4) N,N′:N′′,N′′′)dizinc tetra­kis­(tetra­fluorido­borate) aceto­nitrile tris­olvate Alexandru, Maria-Gabriela Dumitru, Florina Acta Crystallogr E Crystallogr Commun Data Reports The asymmetric unit of the title compound, [Zn(2)(C(25)H(20)N(4))(3)](BF(4))(4)·3CH(3)CN, consists of one dinuclear Zn(II) complex cation with a triple-helical [Zn(2) L (3)](4+) motif (L is bis­{4-[(pyridin-2-yl­methyl­idene)amino]­phen­yl}methane), four BF(4) (−) anions and three CH(3)CN solvent mol­ecules. The Zn⋯Zn separation is 11.3893 (14) Å and the ligands wrap around the two Zn(II) atoms, forming a triple helix as defined by the Zn—N—N—Zn torsion angles of 104.05 (18), 99.06 (19) and 101.40 (19)°. The Zn—N(pyrid­yl) distances in the octahedral ZnN(6) coordination sphere are in the range 2.128 (5)–2.190 (5) Å and the Zn—N(imine) distances are in the range 2.157 (5)–2.277 (5) Å. International Union of Crystallography 2015-12-31 /pmc/articles/PMC4719869/ /pubmed/26870460 http://dx.doi.org/10.1107/S205698901502455X Text en © Alexandru and Dumitru 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Alexandru, Maria-Gabriela
Dumitru, Florina
Crystal structure of tris­(μ-bis­{4-[(pyridin-2-yl­methyl­idene)amino]­phen­yl}methane-κ(4) N,N′:N′′,N′′′)dizinc tetra­kis­(tetra­fluorido­borate) aceto­nitrile tris­olvate
title Crystal structure of tris­(μ-bis­{4-[(pyridin-2-yl­methyl­idene)amino]­phen­yl}methane-κ(4) N,N′:N′′,N′′′)dizinc tetra­kis­(tetra­fluorido­borate) aceto­nitrile tris­olvate
title_full Crystal structure of tris­(μ-bis­{4-[(pyridin-2-yl­methyl­idene)amino]­phen­yl}methane-κ(4) N,N′:N′′,N′′′)dizinc tetra­kis­(tetra­fluorido­borate) aceto­nitrile tris­olvate
title_fullStr Crystal structure of tris­(μ-bis­{4-[(pyridin-2-yl­methyl­idene)amino]­phen­yl}methane-κ(4) N,N′:N′′,N′′′)dizinc tetra­kis­(tetra­fluorido­borate) aceto­nitrile tris­olvate
title_full_unstemmed Crystal structure of tris­(μ-bis­{4-[(pyridin-2-yl­methyl­idene)amino]­phen­yl}methane-κ(4) N,N′:N′′,N′′′)dizinc tetra­kis­(tetra­fluorido­borate) aceto­nitrile tris­olvate
title_short Crystal structure of tris­(μ-bis­{4-[(pyridin-2-yl­methyl­idene)amino]­phen­yl}methane-κ(4) N,N′:N′′,N′′′)dizinc tetra­kis­(tetra­fluorido­borate) aceto­nitrile tris­olvate
title_sort crystal structure of tris­(μ-bis­{4-[(pyridin-2-yl­methyl­idene)amino]­phen­yl}methane-κ(4) n,n′:n′′,n′′′)dizinc tetra­kis­(tetra­fluorido­borate) aceto­nitrile tris­olvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719869/
https://www.ncbi.nlm.nih.gov/pubmed/26870460
http://dx.doi.org/10.1107/S205698901502455X
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