Crystal structure of bis­(quinolin-1-ium) tetra­chlorido­ferrate(III) chloride

The asymmetric unit of the title hybrid compound, (C(9)H(8)N)[FeCl(4)]Cl, comprises a tetra­hedral tetra­chlorido­ferrate(III) anion, [FeCl(4)](−), a Cl(−) anion and two quinolinium cations. There are N—H⋯Cl hydrogen-bonding inter­actions between the protonated N atoms of the quinolinium cations and...

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Detalles Bibliográficos
Autores principales: Boudjarda, Azzedine, Bouchouit, Karim, Arroudj, Samiha, Bouacida, Sofiane, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719870/
https://www.ncbi.nlm.nih.gov/pubmed/26870461
http://dx.doi.org/10.1107/S2056989015024548
Descripción
Sumario:The asymmetric unit of the title hybrid compound, (C(9)H(8)N)[FeCl(4)]Cl, comprises a tetra­hedral tetra­chlorido­ferrate(III) anion, [FeCl(4)](−), a Cl(−) anion and two quinolinium cations. There are N—H⋯Cl hydrogen-bonding inter­actions between the protonated N atoms of the quinolinium cations and the chloride anion, which together with π–π stacking between adjacent quinolinium rings [centroid-to-centroid distances between C(6) and C(5)N rings in adjacent stacked quinolinium cations of 3.609 (2) and 3.802 (2) Å] serve to hold the structure together.

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