Crystal structure of bis­(quinolin-1-ium) tetra­chlorido­ferrate(III) chloride

The asymmetric unit of the title hybrid compound, (C(9)H(8)N)[FeCl(4)]Cl, comprises a tetra­hedral tetra­chlorido­ferrate(III) anion, [FeCl(4)](−), a Cl(−) anion and two quinolinium cations. There are N—H⋯Cl hydrogen-bonding inter­actions between the protonated N atoms of the quinolinium cations and...

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Autores principales: Boudjarda, Azzedine, Bouchouit, Karim, Arroudj, Samiha, Bouacida, Sofiane, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719870/
https://www.ncbi.nlm.nih.gov/pubmed/26870461
http://dx.doi.org/10.1107/S2056989015024548
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author Boudjarda, Azzedine
Bouchouit, Karim
Arroudj, Samiha
Bouacida, Sofiane
Merazig, Hocine
author_facet Boudjarda, Azzedine
Bouchouit, Karim
Arroudj, Samiha
Bouacida, Sofiane
Merazig, Hocine
author_sort Boudjarda, Azzedine
collection PubMed
description The asymmetric unit of the title hybrid compound, (C(9)H(8)N)[FeCl(4)]Cl, comprises a tetra­hedral tetra­chlorido­ferrate(III) anion, [FeCl(4)](−), a Cl(−) anion and two quinolinium cations. There are N—H⋯Cl hydrogen-bonding inter­actions between the protonated N atoms of the quinolinium cations and the chloride anion, which together with π–π stacking between adjacent quinolinium rings [centroid-to-centroid distances between C(6) and C(5)N rings in adjacent stacked quinolinium cations of 3.609 (2) and 3.802 (2) Å] serve to hold the structure together.
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spelling pubmed-47198702016-02-11 Crystal structure of bis­(quinolin-1-ium) tetra­chlorido­ferrate(III) chloride Boudjarda, Azzedine Bouchouit, Karim Arroudj, Samiha Bouacida, Sofiane Merazig, Hocine Acta Crystallogr E Crystallogr Commun Data Reports The asymmetric unit of the title hybrid compound, (C(9)H(8)N)[FeCl(4)]Cl, comprises a tetra­hedral tetra­chlorido­ferrate(III) anion, [FeCl(4)](−), a Cl(−) anion and two quinolinium cations. There are N—H⋯Cl hydrogen-bonding inter­actions between the protonated N atoms of the quinolinium cations and the chloride anion, which together with π–π stacking between adjacent quinolinium rings [centroid-to-centroid distances between C(6) and C(5)N rings in adjacent stacked quinolinium cations of 3.609 (2) and 3.802 (2) Å] serve to hold the structure together. International Union of Crystallography 2015-12-31 /pmc/articles/PMC4719870/ /pubmed/26870461 http://dx.doi.org/10.1107/S2056989015024548 Text en © Boudjarda et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Boudjarda, Azzedine
Bouchouit, Karim
Arroudj, Samiha
Bouacida, Sofiane
Merazig, Hocine
Crystal structure of bis­(quinolin-1-ium) tetra­chlorido­ferrate(III) chloride
title Crystal structure of bis­(quinolin-1-ium) tetra­chlorido­ferrate(III) chloride
title_full Crystal structure of bis­(quinolin-1-ium) tetra­chlorido­ferrate(III) chloride
title_fullStr Crystal structure of bis­(quinolin-1-ium) tetra­chlorido­ferrate(III) chloride
title_full_unstemmed Crystal structure of bis­(quinolin-1-ium) tetra­chlorido­ferrate(III) chloride
title_short Crystal structure of bis­(quinolin-1-ium) tetra­chlorido­ferrate(III) chloride
title_sort crystal structure of bis­(quinolin-1-ium) tetra­chlorido­ferrate(iii) chloride
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719870/
https://www.ncbi.nlm.nih.gov/pubmed/26870461
http://dx.doi.org/10.1107/S2056989015024548
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