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Crystal structure of tri­hydrogen bis­{[1,1,1-tris­(2-oxido­ethyl­amino­meth­yl)ethane]­cobalt(III)} trinitrate

The title compound, [Co(2)(L)(2)](3+)·3NO(3) (−) [where L = CH(3)C(CH(2)NHCH(2)CH(2)OH(1/2))(3)], has been synthesized from the ligand 1,1,1-tris­(2-hy­droxy­ethyl­amino­meth­yl)ethane. The cobalt(III) dimer has an inter­esting and uncommon O—H⋯O hydrogen-bonding motif with the three bridging hy­dro...

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Detalles Bibliográficos
Autores principales: Sethi, Waqas, Johannesen, Heini V., Morsing, Thorbjørn J., Piligkos, Stergios, Weihe, Høgni
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719871/
https://www.ncbi.nlm.nih.gov/pubmed/26870462
http://dx.doi.org/10.1107/S2056989015024664
Descripción
Sumario:The title compound, [Co(2)(L)(2)](3+)·3NO(3) (−) [where L = CH(3)C(CH(2)NHCH(2)CH(2)OH(1/2))(3)], has been synthesized from the ligand 1,1,1-tris­(2-hy­droxy­ethyl­amino­meth­yl)ethane. The cobalt(III) dimer has an inter­esting and uncommon O—H⋯O hydrogen-bonding motif with the three bridging hy­droxy H atoms each being equally disordered over two positions. In the dimeric trication, the octa­hedrally coordinated Co(III) atoms and the capping C atoms lie on a threefold rotation axis. The N atoms of two crystallographically independent nitrate anions also lie on threefold rotation axes. N—H⋯O hydrogen bonding between the complex cations and nitrate anions leads to the formation of a three-dimensional network structure. The compound is a racemic conglomerate of crystals containing either d or l mol­ecules. The crystal used for this study is a d crystal.