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Crystal structure of trihydrogen bis{[1,1,1-tris(2-oxidoethylaminomethyl)ethane]cobalt(III)} trinitrate
The title compound, [Co(2)(L)(2)](3+)·3NO(3) (−) [where L = CH(3)C(CH(2)NHCH(2)CH(2)OH(1/2))(3)], has been synthesized from the ligand 1,1,1-tris(2-hydroxyethylaminomethyl)ethane. The cobalt(III) dimer has an interesting and uncommon O—H⋯O hydrogen-bonding motif with the three bridging hydro...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719871/ https://www.ncbi.nlm.nih.gov/pubmed/26870462 http://dx.doi.org/10.1107/S2056989015024664 |
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author | Sethi, Waqas Johannesen, Heini V. Morsing, Thorbjørn J. Piligkos, Stergios Weihe, Høgni |
author_facet | Sethi, Waqas Johannesen, Heini V. Morsing, Thorbjørn J. Piligkos, Stergios Weihe, Høgni |
author_sort | Sethi, Waqas |
collection | PubMed |
description | The title compound, [Co(2)(L)(2)](3+)·3NO(3) (−) [where L = CH(3)C(CH(2)NHCH(2)CH(2)OH(1/2))(3)], has been synthesized from the ligand 1,1,1-tris(2-hydroxyethylaminomethyl)ethane. The cobalt(III) dimer has an interesting and uncommon O—H⋯O hydrogen-bonding motif with the three bridging hydroxy H atoms each being equally disordered over two positions. In the dimeric trication, the octahedrally coordinated Co(III) atoms and the capping C atoms lie on a threefold rotation axis. The N atoms of two crystallographically independent nitrate anions also lie on threefold rotation axes. N—H⋯O hydrogen bonding between the complex cations and nitrate anions leads to the formation of a three-dimensional network structure. The compound is a racemic conglomerate of crystals containing either d or l molecules. The crystal used for this study is a d crystal. |
format | Online Article Text |
id | pubmed-4719871 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-47198712016-02-11 Crystal structure of trihydrogen bis{[1,1,1-tris(2-oxidoethylaminomethyl)ethane]cobalt(III)} trinitrate Sethi, Waqas Johannesen, Heini V. Morsing, Thorbjørn J. Piligkos, Stergios Weihe, Høgni Acta Crystallogr E Crystallogr Commun Data Reports The title compound, [Co(2)(L)(2)](3+)·3NO(3) (−) [where L = CH(3)C(CH(2)NHCH(2)CH(2)OH(1/2))(3)], has been synthesized from the ligand 1,1,1-tris(2-hydroxyethylaminomethyl)ethane. The cobalt(III) dimer has an interesting and uncommon O—H⋯O hydrogen-bonding motif with the three bridging hydroxy H atoms each being equally disordered over two positions. In the dimeric trication, the octahedrally coordinated Co(III) atoms and the capping C atoms lie on a threefold rotation axis. The N atoms of two crystallographically independent nitrate anions also lie on threefold rotation axes. N—H⋯O hydrogen bonding between the complex cations and nitrate anions leads to the formation of a three-dimensional network structure. The compound is a racemic conglomerate of crystals containing either d or l molecules. The crystal used for this study is a d crystal. International Union of Crystallography 2015-12-31 /pmc/articles/PMC4719871/ /pubmed/26870462 http://dx.doi.org/10.1107/S2056989015024664 Text en © Sethi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Sethi, Waqas Johannesen, Heini V. Morsing, Thorbjørn J. Piligkos, Stergios Weihe, Høgni Crystal structure of trihydrogen bis{[1,1,1-tris(2-oxidoethylaminomethyl)ethane]cobalt(III)} trinitrate |
title | Crystal structure of trihydrogen bis{[1,1,1-tris(2-oxidoethylaminomethyl)ethane]cobalt(III)} trinitrate |
title_full | Crystal structure of trihydrogen bis{[1,1,1-tris(2-oxidoethylaminomethyl)ethane]cobalt(III)} trinitrate |
title_fullStr | Crystal structure of trihydrogen bis{[1,1,1-tris(2-oxidoethylaminomethyl)ethane]cobalt(III)} trinitrate |
title_full_unstemmed | Crystal structure of trihydrogen bis{[1,1,1-tris(2-oxidoethylaminomethyl)ethane]cobalt(III)} trinitrate |
title_short | Crystal structure of trihydrogen bis{[1,1,1-tris(2-oxidoethylaminomethyl)ethane]cobalt(III)} trinitrate |
title_sort | crystal structure of trihydrogen bis{[1,1,1-tris(2-oxidoethylaminomethyl)ethane]cobalt(iii)} trinitrate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719871/ https://www.ncbi.nlm.nih.gov/pubmed/26870462 http://dx.doi.org/10.1107/S2056989015024664 |
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