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Crystal structure of tri­hydrogen bis­{[1,1,1-tris­(2-oxido­ethyl­amino­meth­yl)ethane]­cobalt(III)} trinitrate

The title compound, [Co(2)(L)(2)](3+)·3NO(3) (−) [where L = CH(3)C(CH(2)NHCH(2)CH(2)OH(1/2))(3)], has been synthesized from the ligand 1,1,1-tris­(2-hy­droxy­ethyl­amino­meth­yl)ethane. The cobalt(III) dimer has an inter­esting and uncommon O—H⋯O hydrogen-bonding motif with the three bridging hy­dro...

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Autores principales: Sethi, Waqas, Johannesen, Heini V., Morsing, Thorbjørn J., Piligkos, Stergios, Weihe, Høgni
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719871/
https://www.ncbi.nlm.nih.gov/pubmed/26870462
http://dx.doi.org/10.1107/S2056989015024664
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author Sethi, Waqas
Johannesen, Heini V.
Morsing, Thorbjørn J.
Piligkos, Stergios
Weihe, Høgni
author_facet Sethi, Waqas
Johannesen, Heini V.
Morsing, Thorbjørn J.
Piligkos, Stergios
Weihe, Høgni
author_sort Sethi, Waqas
collection PubMed
description The title compound, [Co(2)(L)(2)](3+)·3NO(3) (−) [where L = CH(3)C(CH(2)NHCH(2)CH(2)OH(1/2))(3)], has been synthesized from the ligand 1,1,1-tris­(2-hy­droxy­ethyl­amino­meth­yl)ethane. The cobalt(III) dimer has an inter­esting and uncommon O—H⋯O hydrogen-bonding motif with the three bridging hy­droxy H atoms each being equally disordered over two positions. In the dimeric trication, the octa­hedrally coordinated Co(III) atoms and the capping C atoms lie on a threefold rotation axis. The N atoms of two crystallographically independent nitrate anions also lie on threefold rotation axes. N—H⋯O hydrogen bonding between the complex cations and nitrate anions leads to the formation of a three-dimensional network structure. The compound is a racemic conglomerate of crystals containing either d or l mol­ecules. The crystal used for this study is a d crystal.
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spelling pubmed-47198712016-02-11 Crystal structure of tri­hydrogen bis­{[1,1,1-tris­(2-oxido­ethyl­amino­meth­yl)ethane]­cobalt(III)} trinitrate Sethi, Waqas Johannesen, Heini V. Morsing, Thorbjørn J. Piligkos, Stergios Weihe, Høgni Acta Crystallogr E Crystallogr Commun Data Reports The title compound, [Co(2)(L)(2)](3+)·3NO(3) (−) [where L = CH(3)C(CH(2)NHCH(2)CH(2)OH(1/2))(3)], has been synthesized from the ligand 1,1,1-tris­(2-hy­droxy­ethyl­amino­meth­yl)ethane. The cobalt(III) dimer has an inter­esting and uncommon O—H⋯O hydrogen-bonding motif with the three bridging hy­droxy H atoms each being equally disordered over two positions. In the dimeric trication, the octa­hedrally coordinated Co(III) atoms and the capping C atoms lie on a threefold rotation axis. The N atoms of two crystallographically independent nitrate anions also lie on threefold rotation axes. N—H⋯O hydrogen bonding between the complex cations and nitrate anions leads to the formation of a three-dimensional network structure. The compound is a racemic conglomerate of crystals containing either d or l mol­ecules. The crystal used for this study is a d crystal. International Union of Crystallography 2015-12-31 /pmc/articles/PMC4719871/ /pubmed/26870462 http://dx.doi.org/10.1107/S2056989015024664 Text en © Sethi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Sethi, Waqas
Johannesen, Heini V.
Morsing, Thorbjørn J.
Piligkos, Stergios
Weihe, Høgni
Crystal structure of tri­hydrogen bis­{[1,1,1-tris­(2-oxido­ethyl­amino­meth­yl)ethane]­cobalt(III)} trinitrate
title Crystal structure of tri­hydrogen bis­{[1,1,1-tris­(2-oxido­ethyl­amino­meth­yl)ethane]­cobalt(III)} trinitrate
title_full Crystal structure of tri­hydrogen bis­{[1,1,1-tris­(2-oxido­ethyl­amino­meth­yl)ethane]­cobalt(III)} trinitrate
title_fullStr Crystal structure of tri­hydrogen bis­{[1,1,1-tris­(2-oxido­ethyl­amino­meth­yl)ethane]­cobalt(III)} trinitrate
title_full_unstemmed Crystal structure of tri­hydrogen bis­{[1,1,1-tris­(2-oxido­ethyl­amino­meth­yl)ethane]­cobalt(III)} trinitrate
title_short Crystal structure of tri­hydrogen bis­{[1,1,1-tris­(2-oxido­ethyl­amino­meth­yl)ethane]­cobalt(III)} trinitrate
title_sort crystal structure of tri­hydrogen bis­{[1,1,1-tris­(2-oxido­ethyl­amino­meth­yl)ethane]­cobalt(iii)} trinitrate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719871/
https://www.ncbi.nlm.nih.gov/pubmed/26870462
http://dx.doi.org/10.1107/S2056989015024664
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