Crystal structure of (eth­oxy­ethyl­idene)di­methyl­aza­nium ethyl sulfate

In the title salt, C(6)H(14)NO(+)·C(2)H(5)SO(4) (−), the C—N bond lengths in the cation are 1.2981 (14), 1.4658 (14) and 1.4707 (15) Å, indicating double- and single-bond character, respectively. The C—O bond length of 1.3157 (13) Å shows double-bond character, indicating charge delocalization withi...

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Autores principales: Tiritiris, Ioannis, Saur, Stefan, Kantlehner, Willi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719878/
https://www.ncbi.nlm.nih.gov/pubmed/26870525
http://dx.doi.org/10.1107/S2056989015020678
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author Tiritiris, Ioannis
Saur, Stefan
Kantlehner, Willi
author_facet Tiritiris, Ioannis
Saur, Stefan
Kantlehner, Willi
author_sort Tiritiris, Ioannis
collection PubMed
description In the title salt, C(6)H(14)NO(+)·C(2)H(5)SO(4) (−), the C—N bond lengths in the cation are 1.2981 (14), 1.4658 (14) and 1.4707 (15) Å, indicating double- and single-bond character, respectively. The C—O bond length of 1.3157 (13) Å shows double-bond character, indicating charge delocalization within the NCO plane of the iminium ion. In the crystal, C—H⋯O hydrogen bonds between H atoms of the cations and O atoms of neighbouring ethyl sulfate anions are present, generating a three-dimensional network.
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spelling pubmed-47198782016-02-11 Crystal structure of (eth­oxy­ethyl­idene)di­methyl­aza­nium ethyl sulfate Tiritiris, Ioannis Saur, Stefan Kantlehner, Willi Acta Crystallogr E Crystallogr Commun Data Reports In the title salt, C(6)H(14)NO(+)·C(2)H(5)SO(4) (−), the C—N bond lengths in the cation are 1.2981 (14), 1.4658 (14) and 1.4707 (15) Å, indicating double- and single-bond character, respectively. The C—O bond length of 1.3157 (13) Å shows double-bond character, indicating charge delocalization within the NCO plane of the iminium ion. In the crystal, C—H⋯O hydrogen bonds between H atoms of the cations and O atoms of neighbouring ethyl sulfate anions are present, generating a three-dimensional network. International Union of Crystallography 2015-11-07 /pmc/articles/PMC4719878/ /pubmed/26870525 http://dx.doi.org/10.1107/S2056989015020678 Text en © Tiritiris et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Tiritiris, Ioannis
Saur, Stefan
Kantlehner, Willi
Crystal structure of (eth­oxy­ethyl­idene)di­methyl­aza­nium ethyl sulfate
title Crystal structure of (eth­oxy­ethyl­idene)di­methyl­aza­nium ethyl sulfate
title_full Crystal structure of (eth­oxy­ethyl­idene)di­methyl­aza­nium ethyl sulfate
title_fullStr Crystal structure of (eth­oxy­ethyl­idene)di­methyl­aza­nium ethyl sulfate
title_full_unstemmed Crystal structure of (eth­oxy­ethyl­idene)di­methyl­aza­nium ethyl sulfate
title_short Crystal structure of (eth­oxy­ethyl­idene)di­methyl­aza­nium ethyl sulfate
title_sort crystal structure of (eth­oxy­ethyl­idene)di­methyl­aza­nium ethyl sulfate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719878/
https://www.ncbi.nlm.nih.gov/pubmed/26870525
http://dx.doi.org/10.1107/S2056989015020678
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