Crystal structure of (5Z)-5-(5-bromo-2-hy­droxy­benzyl­idene)-1,3-thia­zolidine-2,4-dione

In the title compound, C(10)H(6)BrNO(3)S, the dihedral angle between the thia­zolidine ring (r.m.s. deviation = 0.014 Å) and the benzene ring is 5.78 (14)°. The S atom of the heterocyclic ring is syn to the OH group attached to the benzene ring. In the crystal, inversion dimers linked by pairs of N—...

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Detalles Bibliográficos
Autores principales: Mague, Joel T., Mohamed, Shaaban K., Akkurt, Mehmet, Younes, Sabry H. H., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719880/
https://www.ncbi.nlm.nih.gov/pubmed/26870527
http://dx.doi.org/10.1107/S2056989015020654
Descripción
Sumario:In the title compound, C(10)H(6)BrNO(3)S, the dihedral angle between the thia­zolidine ring (r.m.s. deviation = 0.014 Å) and the benzene ring is 5.78 (14)°. The S atom of the heterocyclic ring is syn to the OH group attached to the benzene ring. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops. The dimers are linked into [001] ribbons by pairwise O—H⋯O hydrogen bonds with R (2) (2)(18) motifs. There are no short contacts involving the Br atom.

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