Crystal structure of (5Z)-5-(5-bromo-2-hy­droxy­benzyl­idene)-1,3-thia­zolidine-2,4-dione

In the title compound, C(10)H(6)BrNO(3)S, the dihedral angle between the thia­zolidine ring (r.m.s. deviation = 0.014 Å) and the benzene ring is 5.78 (14)°. The S atom of the heterocyclic ring is syn to the OH group attached to the benzene ring. In the crystal, inversion dimers linked by pairs of N—...

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Autores principales: Mague, Joel T., Mohamed, Shaaban K., Akkurt, Mehmet, Younes, Sabry H. H., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719880/
https://www.ncbi.nlm.nih.gov/pubmed/26870527
http://dx.doi.org/10.1107/S2056989015020654
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author Mague, Joel T.
Mohamed, Shaaban K.
Akkurt, Mehmet
Younes, Sabry H. H.
Albayati, Mustafa R.
author_facet Mague, Joel T.
Mohamed, Shaaban K.
Akkurt, Mehmet
Younes, Sabry H. H.
Albayati, Mustafa R.
author_sort Mague, Joel T.
collection PubMed
description In the title compound, C(10)H(6)BrNO(3)S, the dihedral angle between the thia­zolidine ring (r.m.s. deviation = 0.014 Å) and the benzene ring is 5.78 (14)°. The S atom of the heterocyclic ring is syn to the OH group attached to the benzene ring. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops. The dimers are linked into [001] ribbons by pairwise O—H⋯O hydrogen bonds with R (2) (2)(18) motifs. There are no short contacts involving the Br atom.
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spelling pubmed-47198802016-02-11 Crystal structure of (5Z)-5-(5-bromo-2-hy­droxy­benzyl­idene)-1,3-thia­zolidine-2,4-dione Mague, Joel T. Mohamed, Shaaban K. Akkurt, Mehmet Younes, Sabry H. H. Albayati, Mustafa R. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(10)H(6)BrNO(3)S, the dihedral angle between the thia­zolidine ring (r.m.s. deviation = 0.014 Å) and the benzene ring is 5.78 (14)°. The S atom of the heterocyclic ring is syn to the OH group attached to the benzene ring. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops. The dimers are linked into [001] ribbons by pairwise O—H⋯O hydrogen bonds with R (2) (2)(18) motifs. There are no short contacts involving the Br atom. International Union of Crystallography 2015-11-07 /pmc/articles/PMC4719880/ /pubmed/26870527 http://dx.doi.org/10.1107/S2056989015020654 Text en © Mague et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Mague, Joel T.
Mohamed, Shaaban K.
Akkurt, Mehmet
Younes, Sabry H. H.
Albayati, Mustafa R.
Crystal structure of (5Z)-5-(5-bromo-2-hy­droxy­benzyl­idene)-1,3-thia­zolidine-2,4-dione
title Crystal structure of (5Z)-5-(5-bromo-2-hy­droxy­benzyl­idene)-1,3-thia­zolidine-2,4-dione
title_full Crystal structure of (5Z)-5-(5-bromo-2-hy­droxy­benzyl­idene)-1,3-thia­zolidine-2,4-dione
title_fullStr Crystal structure of (5Z)-5-(5-bromo-2-hy­droxy­benzyl­idene)-1,3-thia­zolidine-2,4-dione
title_full_unstemmed Crystal structure of (5Z)-5-(5-bromo-2-hy­droxy­benzyl­idene)-1,3-thia­zolidine-2,4-dione
title_short Crystal structure of (5Z)-5-(5-bromo-2-hy­droxy­benzyl­idene)-1,3-thia­zolidine-2,4-dione
title_sort crystal structure of (5z)-5-(5-bromo-2-hy­droxy­benzyl­idene)-1,3-thia­zolidine-2,4-dione
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719880/
https://www.ncbi.nlm.nih.gov/pubmed/26870527
http://dx.doi.org/10.1107/S2056989015020654
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